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ARTIGOS RECENTES - SUSTQUIMAMB NÚMERO ESPECIAL


Artigo

EXPLORANDO O MECANISMO DE DEGRADAÇÃO ENZIMÁTICA DO POLIURETANO (PU) POR MEIO DAS POLIURETANASES ESTERASES A E B (PueA E PueB): UMA ABORDAGEM INTEGRADA DE DOCKING, DINÂMICA MOLECULAR (MD) E QM/MM

Thiago Antonio Valdez Garcia; José Fernando Ruggiero Bachega; Paulo Augusto Netz

Representation of the stages of the study of the enzymatic degradation of polyurethane (PU): (a) docking, (b) molecular dynamics and in (c) the free energy profile of the proposed reaction mechanism.

http://dx.doi.org/10.21577/0100-4042.20240065

Publicado online: outubro 8, 2024
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Uso de coagulantes no tratamento de efluente de lavanderia hospitalar: a busca por processos físico-químicos sustentáveis visando remoção de poluentes e microrganismos patogênicos

Eduarda V. S. GomesI; Iramaia A. MoraesI; Felipe C. MazzaI; Fernanda R. C. DamascenoI,II,*; Juliana O. C. BrumI,III

Physico-chemical treatment of hospital laundry wastewater using aluminum sulfate, tannin and Moringa oleifera seeds aiming for the removal of pollutants and pathogens.

http://dx.doi.org/10.21577/0100-4042.20240064

Publicado online: setembro 30, 2024
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Development of a voltammetric method for the simultaneous determination of pesticides in surface water using a composite electrode

Gleiciane Barros Ferreira da SilvaI,II; Mateus Ferreira AmaralI; Felipe Perin BezerraI; Ailton José TerezoI; Marilza CastilhoI

Graphical abstract of composite electrode as electrochemical material for the simultaneous determination of pesticides in surface water and its oxidation behavior study.

http://dx.doi.org/10.21577/0100-4042.20240062

Publicado online: setembro 27, 2024
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Vestígios do derrame de petróleo de 2019: avaliação da presença de hpa e btex em produtos de pesca

Crislaine F. BertoldiI; Rafael G. DolattoI; Luiz F. L. de OliveiraII; Lennon F. ReisII; Maria C. CanelaII; Julyanne T. B. de MéloIII; Abinoan da S. RodriguesIII; Ana P. PaimIII; Marco T. GrassiI,*

The contamination of ocean water with oil spills can be a potential problem for food security. The study investigated the presence of polycyclic aromatic hydrocarbons (PAH) and benzene, toluene, ethylbenzene, and xylene (BTEX) in fishes from the Brazilian coast and Rio de Janeiro (RJ) had the higher contamination among the samples.

http://dx.doi.org/10.21577/0100-4042.20240063

Publicado online: setembro 27, 2024
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Estudo teórico e experimental de derivados de clorinas e bacterioclorinas visando a sustentabilidade

Andrés C. A. AcevedoI; Juliana K. BilhaI; Priscila R. M. PereiraI; Paula A. J. AraujoII; Marciana P. UlianaI,II,*

Theoretical calculations are tools in predicting sustainable photosensitizing molecules, synthesized derivatives of chlorins and bacteriochlorins. The theoretical data obtained with the Gaussian 09 software using density functional theory (DFT) are similar to experimental spectroscopic data.

http://dx.doi.org/10.21577/0100-4042.20240061

Publicado online: setembro 24, 2024
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Emprego de dispositivos de difusão em filmes finos por gradiente de concentração (DGT) preparados com agarose, um hidrogel ambientalmente amigável, na avaliação da labilidade de cádmio, cobre e cromo em águas naturais

Karine Andréa Costa; Bruna de Fátima Pereira Schmite; Renata Martins da Silva; Vanessa Egéa dos Anjos*

Homemade diffusive gradients in thin films (DGT) devices prepared with agarose (non-toxic hydrogel) to evaluate the lability of metallic species in Cará-Cará River, Ponta Grossa, Paraná, Brazil.

http://dx.doi.org/10.21577/0100-4042.20240059

Publicado online: setembro 13, 2024
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Validação de método analítico para quantificação dos estrógenos naturais (E1, E2 e E3) e sintético (EE2) em água superficial e material particulado em suspensão de um estuário subtropical do Atlântico Sul, Brasil

Pedro Toledo NettoI,*; Marcos Canto MachadoII; Luiz Laureno Mafra JúniorI; César C. MartinsIII

Here, we present the validation items studied and the distribution of the estrogen 17α-ethinyl estradiol in suspended particulate matter along a salinity gradient in Guaratuba Bay, South Atlantic, Brazil, during summer and winter.

http://dx.doi.org/10.21577/0100-4042.20240057

Publicado online: agosto 28, 2024
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Photocatalytic water splitting using the semiconductor heterojunction between MoO3-X/CDS

Felipe L. N. SousaI; Luana B. C. OliveiraI,II; Lizeth Carolina MojicaI; Leonardo J. L. MacielI; Wellington de Souza FerreiraI,II;
Denilson V. FreitasI; Marco A. S. GarciaIII; Walter M. AzevedoII; Giovanna MachadoI,*

From gamma irradiation of molybdenum oxide, reduced oxides (MoO3-x) were obtained with expansion of the absorption spectral region. With the heterojunction formation between MoO3-x and cadmium sulfide (CdS) quantum dots, better efficiencies for photocatalytic generation of hydrogen and oxygen are achieved.

http://dx.doi.org/10.21577/0100-4042.20240056

Publicado online: agosto 23, 2024
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Métricas da química analítica verde na avaliação de método ecológico para determinação de defensivos agrícolas por CLAE-DAD

Larissa P. dos SantosI; Bárbara E. A. de MagalhãesII; Walter N. L. dos SantosI,II; Luciana B. OliveiraIII; Madson de G. PereiraI; Débora de A. SantanaI,*

The use of ethanol as a mobile phase allowed good chromatographic separation with excellent evaluation by Green Analytical Chemistry metrics.

http://dx.doi.org/10.21577/0100-4042.20240054

Publicado online: agosto 12, 2024
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Occurrence of polybrominated diphenyl ethers (PBDEs) in surface sediments of an urban artificial lake in Brazil

Fernando F. SodréI,*; Daniel Luiz R. AnnunciaçãoII; Fernanda V. AlmeidaII

Investigation of polybrominated diphenyl ethers (PBDE) levels in Paranoá Lake sediments revealed higher concentrations attributed to effluent discharges from wastewater treatment plants and storm drainage water systems.

http://dx.doi.org/10.21577/0100-4042.20240053

Publicado online: agosto 1, 2024
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Efficient and reusable materials with pyrochlore structure for removing red dye from aqueous media

Valber E. S. FirminoI; Júlia B. R. FernandesI; Marcelo J. B. SouzaII; Anne M. Garrido PedrosaI,*

Efficient and reusable adsorbents with pyrochlore structure can be synthesized by a simple route and applied to remove pollutants from aqueous media.

http://dx.doi.org/10.21577/0100-4042.20240052

Publicado online: julho 24, 2024
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Multiresidue and multiclass determination of Current-use Pesticides (CUPs) in water samples BY SPE and UHPLC-MS/MS

Állisson A. da S. Avellar; Gabriel A. B. Prates; Larissa da S. Alves; Osmar D. Prestes; Martha B. Adaime; Renato Zanella*

A multiresidue and multiclass method was developed for the determination of current-use pesticides (CUPs) in water samples using solid phase extraction (SPE) with polymeric sorbent and ultra-high performance liquid chromatography with tandem mass spectrometry (UHPLC-MS/MS).

http://dx.doi.org/10.21577/0100-4042.20240051

Publicado online: julho 2, 2024
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Revisão

MULTIRESIDUE DETERMINATION OF PESTICIDES IN EXOTIC FRUITS: A REVIEW OF THE ANALYTICAL STRATEGIES AND RESIDUE OCCURRENCE

Rafael Bel Prestes da Silva; Júlia Antunes de Oliveira; Cleusa Fátima Zanchin; Pimpernelli Jonco dos Santos; Osmar Damian Prestes; Renato Zanella

This review aims to provide an overview of the methods for determining pesticide residues in exotic fruits, focusing on the strategies employed by these methods and the occurrence of pesticide residues.

http://dx.doi.org/10.21577/0100-4042.20240066

Publicado online: outubro 10, 2024
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Educação

ABORDAGEM DA EDUCAÇÃO AMBIENTAL NO ENSINO DE QUÍMICA: UMA ANÁLISE A PARTIR DE ARTIGOS PUBLICADOS NA REVISTA QUÍMICA NOVA NA ESCOLA (QNEsc)

Sergiana S. de Oliveira Aprigio; Maria Vitória L. Nascimento; Leonardo B. Cantanhede; Severina C. da Silva Cantanhede;
Osiel C. da Trindade Junior; Douglas R. e Silva Barbosa; Lidiane da Silva Araújo

Teaching chemistry as a tool for sustainability based on discussions of environmental chemistry in the classroom: challenges and achievements in 27 years of disseminating research in chemical education through the journal Quimica Nova na Escola (QNESc).

http://dx.doi.org/10.21577/0100-4042.20240067

Publicado online: outubro 15, 2024
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Educación sostenible y salud humana en la sociedad: reflexiones sobre la influencia de la química verde pospandemia

Romina A. Arreche; Patricia G. Vázquez*

This work will focus on Sustainable Development Goals 3 and 4, respectively, which will be achieved if citizens have a sustainable education. This plays an important role in having a healthy life.

http://dx.doi.org/10.21577/0100-4042.20240060

Publicado online: setembro 18, 2024
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Sustentabilidade e ODS nas páginas: uma análise de conteúdo dos livros didáticos do PNLD 2021 no contexto da química

Iasmyn P. SilvaI; Kleber M. L. FerreiraII; Paula S. PintoI; Tamyris T. da CunhaII,*

Qualitative research employing Bardin's content analysis methodology: this study delves into the approach of Sustainability and Sustainable Development Goals (SDGs) in textbooks of Natural Science area, specifically within Chemistry context.

http://dx.doi.org/10.21577/0100-4042.20240058

Publicado online: setembro 10, 2024
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Síntese sustentável do ácido L-piroglutâmico: experimento integrado de síntese orgânica e estereoquímica

Fernando Alves BarrettoI; Leonardo AntonelliI; Silvio CunhaI,II,*

(S)-Pyroglutamic acid solvent-free synthesis in undergraduate experimental classes to reinforce sustainable preparation and understanding of properties of chiral compounds in the solid state.

http://dx.doi.org/10.21577/0100-4042.20240055

Publicado online: agosto 16, 2024
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Educação química para um futuro sustentável: desvendando a cinética química da pirólise do resíduo da cultura de pimenta-do-reino (Piper Nigrum L.) para a potencial produção de bio-óleo

Gyovana L. Welsing; Bruna M. Damm; Maria F. F. Lelis*; Marta A. MachadoI; Paulo R. G. Moura

Biomass is a promising raw material for energy generation and is relevant to be used in chemistry education by enabling the discussion about sustainable development goals (SDGs). For higher education, it is recommended that planning and execution be based on problematized experimental activity (PEA).

http://dx.doi.org/10.21577/0100-4042.20240050

Publicado online: julho 2, 2024
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Mechanochemistry applied to the synthesis of 2-phenylimidazo[1,2-α]pyridine as a teaching tool for green chemistry

José S. S. Neto; Leonardo Victor E. Guimarães; Filipe T. Coelho; Luciano M. Lião*; Felipe L. Coelho*

Green chemistry principles are introduced to undergraduate students as an experimental class applying mechanochemistry to prepare both 2-bromoacetophenone and 2-phenylimidazo[1,2-α]pyridine through manual grinding and vortex mixing.

http://dx.doi.org/10.21577/0100-4042.20240048

Publicado online: maio 9, 2024
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Assuntos Gerais

Sustainability, sustainable development, sustainable chemistry, and green chemistry: parallels and interconnections

Acacio S. de Souza*; Patricia G. Ferreira; Iva S. de Jesus; Alcione S. de Carvalho; Debora O. Futuro; Vitor F. Ferreira*

Sustainability, sustainable development, sustainable chemistry and green chemistry are very close and closely interconnected topics, but they present very different concepts.

http://dx.doi.org/10.21577/0100-4042.20240049

Publicado online: junho 28, 2024
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