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23:44, qua nov 5

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ARTIGOS RECENTES


Artigo

EFFECTS OF ALKALI ION DOPING ON MICROSTRUCTURE AND MORPHOLOGY OF RUTILE TITANIUM DIOXIDE THIN FILMS

Felipe L. N. Sousa; Lizeth Carolina Mojica-Sánchez; Denilson Vasconcelos Freitas; Larissa G. C. Silva; Iasmin B. Cavalcanti; Luana B. C. Oliveira; Giovanna Machado

In this research, a TiO2 film matrix was prepared, and the effects of an alkali metal doping process (K, Rb, and Cs) were evaluated by monitoring its morphological, electrical, and structural evolution. The aim was to facilitate green hydrogen production and solar energy conversion.

http://dx.doi.org/10.21577/0100-4042.20250240

Publicado online: novembro 3, 2025
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Total access: 80

MICROWAVE-ASSISTED HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF TiO2 NANOPARTICLES AND EVALUATION OF THEIR PHOTOCATALYTIC PERFORMANCE

Rafael G. Ferreira; Tamara P. da Silva; Mariandry D. V. R. Rodriguez; Jairo L. Rodrigues; André S. Afonso; Márcio C. Pereira;
Douglas S. Monteiro

Microwave-assisted hydrothermal synthesis of TiO2 nanoparticles using titanium(IV) isopropoxide (TIP) and tetramethylammonium hydroxide (TMAH) yields anatase-phase nanostructures. One- and two-step heating produced particles with different morphologies and surface areas. Both samples demonstrated high photocatalytic efficiency in degrading rhodamine B under ultraviolet-visible (UV) light.

http://dx.doi.org/10.21577/0100-4042.20250239

Publicado online: novembro 3, 2025
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Total access: 70

ELECTROSPUN POLYAMIDE 6 NANOFIBERS AS CONTROLLED DELIVERY SYSTEM FOR ENHANCED PHOTODYNAMIC THERAPY

Juliana Pirajá; Aline R. F. Teixeira; Irina M. Factori; Anderson F. Sepulveda; Luiz F. G. Setz; Anderson O. Ribeiro; Wendel A. Alves

Electrospun polyamide 6 (PA-6) nanofibers loaded with methylene blue for topical photodynamic therapy.

http://dx.doi.org/10.21577/0100-4042.20250238

Publicado online: outubro 31, 2025
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Total access: 112

ESTUDOS BIOFÍSICOS ENTRE BENDAMUSTINA, UM AGENTE ANTITUMORAL ALQUILANTE, E O DNA: CONTRIBUIÇÕES PARA O ENTENDIMENTO DO PROCESSO DE INTERAÇÃO

Victorya G. Silva Medeiros; Carla de A. Vital; Ari S. Guimarães; Isis M. Figueiredo; Josué Carinhanha C. Santos

Bendamustine forms a stable and complex with CT-DNA (calf thymus-deoxyribonucleic acid) by non-covalent interactions and non-intercalating binding, suggesting a new antineoplastic mechanism.

http://dx.doi.org/10.21577/0100-4042.20250237

Publicado online: outubro 30, 2025
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Total access: 190

LEACHING CATHODE METAL IONS FROM SPENT LiFePO4 POWER BATTERIES USING LACTIC ACIDBASED DEEP EUTECTIC SOLVENTS

Jianjiao Jin; Jinbao Gao; Chongyu Li; Zhang Yuan; Pengxin Yuan; Chenyun Zhang; Minhao Cao; Xinyang Wu; Tianjun Xiao

This study employs an eco-friendly lactic acid-based deep eutectic solvent (DES) for leaching and recycling metal ions from spent LiFePO4. The prepared DES achieves a Li leaching efficiency of 94.57% and an Fe leaching efficiency of 92.98% under optimal conditions.

http://dx.doi.org/10.21577/0100-4042.20250236

Publicado online: outubro 30, 2025
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Total access: 88

DIGITAL IMAGE PROCESSING AND MACHINE LEARNING AS AN ENHANCEMENT OF THE SCOTT TEST

Roberta C. Testa; João G. Soethe; Isabella F. Melo; Vanderlei A. de Lima; Andressa Galli

The graphical abstract summarizes the colorimetric Scott test for cocaine detection, image processing with GIMP® (GNU Image Manipulation Program), color parameter extraction in ChemoStat®, collinearity analysis in RStudio®, and classification algorithm evaluation based on performance metrics.

http://dx.doi.org/10.21577/0100-4042.20250234

Publicado online: outubro 28, 2025
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Total access: 162

ESTUDO DA ATIVIDADE CATALÍTICA DO COMPLEXO [RuCl2(p-cimeno)]2 NA METÁTESE/ISOMERIZAÇÃO DE OLEFINAS DE ALILBENZENOS SUBSTITUÍDOS

Alexandre D. Pereira; Aline A. C. França; Adny G. O. Viana; Beatriz S. Silva; Roseane S. S. de Carvalho; José A. de Sousa;
Eliada A. da Silva; Benedito S. Lima Neto; José M. E. de Matos; José Luiz S. Sá

The [RuCl2(p-cymene)]2 complex promotes the isomerization and olefin metathesis of substituted allylbenzenes (methyleugenol, eugenol, and estragole), highlighting the influence of catalyst-to-substrate ratio and olefin acidity on product selectivity.

http://dx.doi.org/10.21577/0100-4042.20250233

Publicado online: outubro 27, 2025
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Total access: 211

ESTUDO DA AUTENTICIDADE DE CÉDULAS DE CEM REAIS POR ESPECTROSCOPIA NA REGIÃO DO INFRAVERMELHO MÉDIO E PRÓXIMO ASSOCIADA A MÉTODOS QUIMIOMÉTRICOS

Anna Clara F. Braz; Jandira M. O. B. Brandão; Nayara A. dos Santos; Márcia H. C. Nascimento; Bruno M. M. Siqueira;
Paulo R. Filgueiras; Wanderson Romão

The study uses infrared spectroscopy techniques to differentiate authentic and counterfeit Brazilian banknotes. Spectral data were analyzed using near-infrared (NIR) and Fourier transform infrared (FTIR) spectroscopy, then processed with Matlab, Origin and Orange.

http://dx.doi.org/10.21577/0100-4042.20250232

Publicado online: outubro 20, 2025
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Total access: 179

AVALIAÇÃO DA EFICIÊNCIA FOTOTÉRMICA DE ÓXIDOS DE GRAFENO REDUZIDOS COM DIFERENTES DIMENSÕES

Isabela A. A. Bessa; Mikaelly O. B. Sousa; Fernanda D. Marques; Elisa Q. C. da Costa; Ana Beatriz C. Souza; Dayenny L. D'Amato; Camille C. de Mello; Diego O. da Costa ; Wilson S. Nascimento; Johnnys S. Hortêncio; Bráulio S. Archanjo; Célia M. Ronconi

Different exfoliation methods were applied to obtain reduced graphene oxide (rGO) with varied lateral sizes. Photothermal studies under near-infrared (NIR) irradiation showed efficient heat generation. Sheet size had minimal influence on the photothermal performance.

http://dx.doi.org/10.21577/0100-4042.20250231

Publicado online: outubro 14, 2025
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Total access: 244

NOVEL DIHYDROPYRIMIDINE-THIONE DERIVATIVES AS CHOLINESTERASE INHIBITORS TARGETING ALZHEIMER'S DISEASE: ADVANCED STRUCTURAL CHARACTERIZATION, COMPUTATIONAL MODELLING AND BIOLOGICAL EVALUATION

Aisha A. Alsfouk; Pervaiz Ali Channar; Aftab Ahmed; Syeda Abida Ejaz ; Aamer Saeed; Tahira Shamim; Rabail Ujan; Hammad Ismail; Michael Bolte; Ulrich Florke; Tuncer Hökelek

The newly synthesized crystal of dihydropyrimidine-thiones were evaluated as cholinesterase inhibitors targeting Alzheimer's disease via comprehensive in vitro and in silico investigations.

http://dx.doi.org/10.21577/0100-4042.20250230

Publicado online: outubro 14, 2025
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Total access: 181

O que o potencial de circuito aberto pode nos informar sobre a resistência à corrosão de ligas de alumínio?

João Victor de S. AraujoI,*; Zehbour PanossianII; Hercílio G. MeloIII; Isolda CostaI

The evolution of open circuit potential (OCP) over time was monitored to evaluate corrosion resistance of aluminium alloys. Localized attack occurred even at more noble potentials. This highlights the limitations of using OCP as a standalone technique for corrosion resistance assessment.

http://dx.doi.org/10.21577/0100-4042.20250229

Publicado online: outubro 10, 2025
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Total access: 219

Scanning electron microscopy: an essential tool in the investigation of cement for oil wells

Rafael A. VenturaI; Eduardo J. C. LinsII; Júlio C. O. FreitasI; Antonio E. MartinelliII,*

The graphical abstract illustrates the use of scanning electron microscopy (SEM) to investigate oil well cement microstructures. Representative SEM images reveal hydration products, carbonation phases, and morphological changes under various conditions.

http://dx.doi.org/10.21577/0100-4042.20250227

Publicado online: outubro 8, 2025
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Total access: 184

Análise química de méis de abelhas sem ferrão nativas do brasil e suas bebidas fermentadas

Juliana M. FeresI; Luís Guilherme P. FeitosaII; Larissa G. EliasI; Tulio Marcos NunesI; Norberto P. LopesII,*

Analysis and qualification by electron spray ionization mass spectrometry (ESI-MS/MS) of fermented beverages from honeys of native bees in Brazil.

http://dx.doi.org/10.21577/0100-4042.20250226

Publicado online: outubro 6, 2025
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Total access: 344

In situ fe doped anodized tio2 nanotubes: characterization and photocurrent response

Gustavo R. S. PaulaI; Andréia R. C. CarneiroII; Leandro A. SantosIII; Dalila C. SicupiraII; Rosa M. R. JunqueiraI*

The Graphical Abstract consists of three scanning electron microscopies obtained in the analysis of TiO2 nanotubes synthesized in the presence and absence of iron ions.

http://dx.doi.org/10.21577/0100-4042.20250224

Publicado online: outubro 6, 2025
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Total access: 200

Simple and green production of lignin nanoparticles using ethanol-water mixtures and ultrasonication

Eduardo G. F. de AlmeidaI; Lucas G. P. TienneII; Braulio S. ArchanjoIII; Felipe S. AlencastroIV; Tiago A. BalbinoI; Renata A. SimãoI*

Two solvent compositions (70 and 90% ethanol, v/v in water) and varying sonication times (0-2 h) were evaluated to investigate their effects on lignin nanoparticle formation, morphology, and size.

http://dx.doi.org/10.21577/0100-4042.20250223

Publicado online: outubro 2, 2025
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Total access: 297

Sustainable obtaining of antileishmanial compounds from Cedrela odorata L. demolition wood as an example of the circular bioeconomy

Paulo Alan D. NogueiraI; Henrique C. dos SantosI; Claudete C. do NascimentoII; Bruno B. JensenIII; Antonia Maria R. FrancoIII; Pamela Emily T. IwabuchiIII; Maria da Paz LimaIV,*

Gedunin-type limonoids obtained from wood residues were evaluated against promastigote forms of Leishmania guyanensis and L. amazonensis.

http://dx.doi.org/10.21577/0100-4042.20250213

Publicado online: setembro 4, 2025
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Total access: 358

Detection of melamine in packaging materials using terahertz time-domain spectroscopy

Shuo ZhangI,#; Yuanrong YangI,#; Kun MengII; Xinyong ZhuII; Longjiang HuangI; Lina SuiI,*; Liyan YuI,*

This study demonstrates the nondestructive testing technique of terahertz time-domain spectroscopy to detect melamine through common packaging materials. Distinct absorption peaks at 2.0 and 2.28 THz enabled quantification with high sensitivity.

http://dx.doi.org/10.21577/0100-4042.20250211

Publicado online: setembro 2, 2025
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Total access: 221

Determinação do flavonoide quercetina em extratos de planta por infravermelho (ATR-FTIR) e quimiometria

Nadia B. da CostaI,*; Matheus F. L. de OliveiraI; Eduardo B. de Almeida JrII; Antônio J. Cantanhede FilhoI; Gilmar S. da SilvaI; Eliane R. de SousaIII

Mid-infrared spectroscopy with attenuated total reflection and chemometric tools were applied to analyze flavonoids in extracts from 15 plant species through exploratory analysis and multivariate calibration.

http://dx.doi.org/10.21577/0100-4042.20250210

Publicado online: setembro 1, 2025
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Total access: 318

Increased solubility and dissolution of gelucire® 50/13 solid dispersions containing carbamazepine

Oscar G. da Silva NetoI,#; Rodrigo M. MartinsII,III,*,#; Denilson L. RochaII; Gustavo L. F. BarbosaIII; Maria E. C. B. RangelII; Wladymyr J. B. de SousaI; Ana R. M. de LimaI; Luis A. P. de FreitasIV

Gelucire® 50/13-based solid dispersions significantly improved the solubility of carbamazepine. The best-performing formulation was characterized physicochemically.

http://dx.doi.org/10.21577/0100-4042.20250209

Publicado online: setembro 1, 2025
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Total access: 264

Efficient treatment of NiII-citric acid complexes in nickel plating effluent using electrocatalytic oxidation-synergistic electrodeposition method and nickel resource recovery

Bingzhao CuiI; Zhigang XieII,III,*; Jun YangIII,*; Xiankang LiuI; Yuhan WangIII; Chenlin XuI; Meiying HuangI,*

This diagram illustrates the anode electrocatalytic oxidation decomplexation pathway and the cathode electrodeposition process for nickel recovery in a system integrating electrocatalytic oxidation with electrodeposition technology for treating NiII-citric acid complexes (Ni-Cit).

http://dx.doi.org/10.21577/0100-4042.20250208

Publicado online: setembro 1, 2025
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Total access: 330

Variante da espectrometria gama para avaliação de Cs-137 em matrizes análogas ao açúcar como requisito de segurança alimentar

Yasmin Marques dos SantosI; Mariana Brayner Cavalcante Freire BezerraI; Isvânia Maria Serafim da Silva LopesII; José Araújo dos Santos JúniorI,*; Romilton dos Santos AmaralI; Josineide Marques do Nascimento SantosI,III; Zahily Herrero FernándezI,III; Beatriz Cardoso Campos de AssunçãoIV; Camilla de Andrade Tenorio CavalcantiV; Keyth Roslyn Barbosa da SilvaI

The Graphical Abstract represents the monitoring of unsupported radionuclide, Cs-137, and the importance of designing an efficient, low-cost methodology with qualitative and quantitative rigor to meet nuclear and food safety criteria.

http://dx.doi.org/10.21577/0100-4042.20250205

Publicado online: agosto 26, 2025
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Total access: 288

Enhancement of curcumin bioavailability using a controlled drug delivery system based on chitosan and green iron oxide nanoparticles (Fe3O4)

Fernanda K. Alves de SouzaI; Maria Laura F. Della CostaI; Marco A. MoralesII; Aroldo G. MagdalenaI,*

Controlled release system of curcumin encapsulated by chitosan and carried by green iron oxide (Fe3O4) nanoparticles to enhance curcumin bioavailability.

http://dx.doi.org/10.21577/0100-4042.20250202

Publicado online: agosto 20, 2025
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Total access: 273

Determination of brodifacoum by gas chromatography coupled to mass spectrometry: a new analytical methodology for the determination of coumarin rodenticides in poisoned foods

Daniel B. SouzaI,II,*; Adriana S. de OliveiraII; Wagner Felippe PachecoIII; Marcos A. S. CostaI

Gas chromatography coupled with mass spectrometry can be used to identify the coumarin brodifacoum in poisoned foods.

http://dx.doi.org/10.21577/0100-4042.20250200

Publicado online: agosto 18, 2025
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Total access: 262

Processo de hidrometalurgia para extração de CuII presente em placas de circuito impresso utilizando peróxido de hidrogênio e ácidos como agente lixiviantes

Camila Ferreira PintoI; Eduarda Maia GuimarãesII; Marquele Amorim TonhelaI; Sandra Cristina DantasII; Ana Claudia Granato MalpassII; Geoffroy Roger Pointer MalpassI,II,*

Hydrochloric acid (HCl) and hexafluorosilicic acid (H2SiF6) are used to extract copper as CuII from printed circuit boards, producing H2 as a byproduct.

http://dx.doi.org/10.21577/0100-4042.20250199

Publicado online: agosto 15, 2025
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Total access: 278


Nota Técnica

Aplicativo GAMMA-GUI: uma interface gráfica amigável para análise exploratória de dados no MATLAB

Diego GalvanI,*,#; Tácito Lucena ConteI,#; João Marcos Marques LiduárioII,#; Jelmir Craveiro de AndradeIII,#;
Patrícia CasarinII,#,; Evandro BonaII,IV,*,#

A Matlab® graphical user interface for exploratory data analysis (EDA) for users unfamiliar with the programming language.

http://dx.doi.org/10.21577/0100-4042.20250206

Publicado online: agosto 28, 2025
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Total access: 379


Educação

Representações multimodais no ensino de química: concepções, desafios e transformações

Emerich SousaI,*; João PaivaII

When a teacher explains molecular geometry using verbal descriptions, chemical formulas, modeling clay, software, and gestures, they integrate multiple modes to highlight the three-dimensional nature of molecules and to show specific characteristics.

http://dx.doi.org/10.21577/0100-4042.20250225

Publicado online: outubro 6, 2025
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Total access: 327

Subsunçores e formação conceitual no ensino superior: indícios de aprendizagem significativa em cinética química

Gyovana L. Welsing*; Lília do E. S. A. de Oliveira; Marta A. Machado; Paulo R. G. de Moura

The investigation of previous knowledge, as well as the stimulation of the anchoring of new information, enriches the teaching of chemistry, especially the teaching of chemical kinetics.

http://dx.doi.org/10.21577/0100-4042.20250207

Publicado online: agosto 29, 2025
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Total access: 257

Estudos de caso interrompidos: produção e aplicação no ensino superior de química

Pablyana L. R. da CunhaI,II; Raíla R. S. AlmondesII; Salete L. QueirozII,*

Three interrupted case studies, based on research articles, were developed and implemented in a scientific communication course.

http://dx.doi.org/10.21577/0100-4042.20250204

Publicado online: agosto 26, 2025
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Total access: 289

An inquiry into structuring concepts in organic chemistry based on the analysis of textbooks and the perspectives of teachers from brazilian universities

Gabrielle O. P. Costa; Pedro C. de Araujo*; Renata T. M. P. de Souza; Matheus S. B. da Silva; Eliana C. F. Spaziani; Ana C. Kasseboehmer

Structuring concepts in organic chemistry through textbooks and university professors' perspectives. The image highlights key topics such as chemical bonding, stereochemistry, structure, and acidity-basicity, reinforcing the need for integrated conceptual understanding in teaching.

http://dx.doi.org/10.21577/0100-4042.20250203

Publicado online: agosto 21, 2025
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Total access: 357

Estudos de caso: possibilidades para o desenvolvimento da educação ambiental crítica na pós-graduação em química

Lisiane B. LimaI; Daniel C. A. RibeiroI; Guilherme L. DornelesI; Carla SirtoriII; Camila G. PassosI,*

This research analyzes the potential of preparing Case Study statements in postgraduate chemistry courses as a means of incorporating the principles of critical Environmental Education.

http://dx.doi.org/10.21577/0100-4042.20250201

Publicado online: agosto 20, 2025
PDF Material Complementar

Total access: 306


Assuntos Gerais

BIOCATÁLISE E MERCADO DE ENZIMAS: TENDÊNCIAS, AVANÇOS TECNOLÓGICOS E IMPACTOS NA BIOECONOMIA

José Langone; Marco Antonio G. de Figueiredo; Marta A. P. Langone

This work presents the rapid expansion of the enzyme market within the chemical and biotechnology sectors, propelled by technological innovation and increasing demand for sustainable industrial solutions.

http://dx.doi.org/10.21577/0100-4042.20250235

Publicado online: outubro 28, 2025
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Total access: 83

A general small language model (slm) approach to examining scientific trends through conference proceedings: application to the 2019 and 2024 annual meetings of the brazilian chemical society

Rubens C. SouzaI; Nathália M. P. RosaII; Julio C. DuarteI,III; Itamar Borges Jr.I,II,*

Small language models (SLMs) were used to create a text database from the 2019 and 2024 Brazilian Chemical Society annual meetings (RASBQs) book of abstracts, enabling a comparison of trends and facilitating statistical analysis. Picture created with the Gemini Chatbot from Google.

http://dx.doi.org/10.21577/0100-4042.20250228

Publicado online: outubro 9, 2025
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Total access: 189

Oppenheimer em Belo Horizonte: um resgate histórico

Cássius K. NascimentoI; Breno R. L. GalvãoII; João P. BragaIII,*

Julius Robert Oppenheimer visited the city of Belo Horizonte in his first trip to Brazil in 1953. In an interview, he said "Brazil's future atomic industry should be located in Minas Gerais".

http://dx.doi.org/10.21577/0100-4042.20250198

Publicado online: agosto 11, 2025
PDF

Total access: 271

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