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EDIÇÃO ATUAL vol. 48, No. 1, 2025



Artigo de Capa
Quim. Nova 2025, 48(1), e-20250017, 1-13

Modelagem de misturas binárias pela aplicação da equação de schröeder-van laar a um conjunto de substâncias com diversidade estrutural

Ursula Paôla Rudolph de MatosI,II; Luana Dezingrini LopesI; Ana Paula ScheerenI; Juliana Maria Forain Miolo SchneiderIII;
Adailton João BortoluzziIV; Helio Gauze BonacorsoV; Itamar Luís GonçalvesVI,*; Aloir Antonio MerloI,*

Mole fraction of 6 and 9 determined through the intersection of the graphs obtained by solving the Schröeder-van Laar equation for the formulation of the binary mixture UR10. Background image is the nematic texture of sample UR10 by polarized optical microscopy.

http://dx.doi.org/10.21577/0100-4042.20250017

Publicado online: junho 4, 2024
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Total access: 401

Artigo de Contra Capa
Quim. Nova 2025, 48(1), e-20250013, 1-14

Hidróxidos duplos lamelares em processos catalíticos para a química fina, degradação de poluentes e geração de energia limpa: uma breve revisão

Luiz Phelipe de Souza TomasoI; Joice Florenço BomfimII; Nakédia M. F. CarvalhoII; Jaqueline Dias SenraII;
Luiz Fernando Brum MaltaI,*

Layered double hydroxides are multifunctional agents as catalytic mediators in reaction processes of paramount importance.

http://dx.doi.org/10.21577/0100-4042.20250013

Publicado online: maio 21, 2024
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Total access: 366

Artigo Quim. Nova 2025, 48(1), e-20250001, 1-7

 

Facile synthesis of functionalized UiO-66-type MOFs for CO2 adsorption

Jinlong GeI,II,*; Xiaoqi JinI,II; Liyuan ZhangI,II; Yuhong JiaoI,II; Qiuqin WangI,II; Yongkui WangI,II; Yan GaoI,II;
Jiaojiao GengI,II; Tianqi WangI,II


UiO-66-type Metal-Organic Frameworks (MOFs) were synthesized with functionalized organic linker. UiO-66-NH2 has the highest CO2 adsorption capacity.

http://dx.doi.org/10.21577/0100-4042.20250001

Publicado online: abril 19, 2024
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Total access: 497

Quim. Nova 2025, 48(1), e-20250004, 1-5

 

Efeito das doses de dejeto líquido de suínos nos atributos físicos, químicos e eletroquímicos em um latossolo do cerrado

Raysa Trindade da SilvaI; Wagner Arruda de JesusI; Mário Rodrigo dos Santos SoaresII; Ariane Isis BarrosI,*; Oscarlina Lúcia dos Santos WeberI


The application of liquid swine waste doses to a clayey Cerrado Oxisol improved its physical, chemical, and electrochemical attributes, leading to an increase in nutrient availability for plants and clay aggregation.

http://dx.doi.org/10.21577/0100-4042.20250004

Publicado online: abril 29, 2024
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Total access: 345

Quim. Nova 2025, 48(1), e-20250005, 1-6

 

Redox potential studies based on scan-rate analysis of the diffusional control and dft calculations of the schiff base [(E)-4-amino-3-((3,5-di-tert-butyl-2-hydroxybenzylidene)amino) benzoic acid]

Rosaly Morales-GuevaraI,II; Dayán Páez-HernándezI; Manuel GacitúaIII,IV,V,*; Juan A. FuentesVI; Alexander CarreñoI,VII,*


Schiff bases (SB) are diverse organic compounds, holding potential in both chemistry and biology. We explored an amino benzoic acid SB that presents a stable intramolecular hydrogen bond by cyclic voltammetric profiles supported by computational protocol to estimate redox potentials.

http://dx.doi.org/10.21577/0100-4042.20250005

Publicado online: abril 29, 2024
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Quim. Nova 2025, 48(1), e-20250007, 1-7

 

Chemical and dereplication studies of Palicourea tomentosa (Aubl.) Borhidi and Their antimicrobial and anticholinesterase activities

Ana J. CecattoI; Anelise S. N. FormagioII; Cleide V. Buzanello-MartinsIII; Caroline FortunaI; Márcia R. P. CabralI; Willian F. da CostaI; Débora C. BaldoquiI; Maria H. SarragiottoI,*


This work deal with the phytochemical and dereplication studies, as well as antimicrobial and anticholinesterase evaluation of Palicourea tomentosa.

http://dx.doi.org/10.21577/0100-4042.20250007

Publicado online: maio 3, 2024
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Total access: 389

Quim. Nova 2025, 48(1), e-20250008, 1-7

 

Desenvolvimento de matriz de sílica aminofuncionalizada como potencial adsorvente de íons Pt4+ em sistemas de pré-concentração para análise por FAAS

Caio V. L. V. do Nascimento; Arthur L. S. de Araújo; Lidiane M. A. de Lima; Filipe C. P. de Sousa; Wagner E. Silva; André F. Lavorante; Mônica F. Belian*


This paper describes a synthesis, and characterization of an organofunctionalized silica (Sil-TMSDT) and its application as a solid phase in the preconcentration (SPE) of Pt4+ ions in aqueous media, using detection by flame atomic absorption spectrometry (FAAS).

http://dx.doi.org/10.21577/0100-4042.20250008

Publicado online: maio 15, 2024
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Total access: 387

Quim. Nova 2025, 48(1), e-20250009, 1-7

 

Amazon acai and pineapple residues induce the enzyme laccase in Pleurotus ostreatus: application to bisphenol a bioremediation

Jhessica Cavalcante de Souza GolveiaI; Elaine Sousa NunesI; Thiago Souza BulhõesI; Jerônimo Raimundo de Oliveira NetoII; Luiz Carlos da CunhaII; Luiza Cintra CamposIII; Mariângela Fontes SantiagoI; Fernando SchimidtIV,*


Bisphenol A (BPA) is challenging to remove in conventional wastewater treatment. In this study, with the laccase enzyme from Pleurotus ostreatus induced by acai berry and pineapple residues, BPA was effectively degraded within 4 hours.

http://dx.doi.org/10.21577/0100-4042.20250009

Publicado online: maio 15, 2024
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Total access: 389

Quim. Nova 2025, 48(1), e-20250010, 1-6

 

Chemical constituents of Amburana acreana Ducke A. C. Sm. leaves

Adrianne B. FerreiraI,* Rosane M. AguiarII; Hugo N. BrandãoIII; Rauldenis A. F. SantosIV; Humberto F. de FreitasIII,V; Catharine TelesV; Joice N. ReisV; Jessica L. de SouzaIII; Clayton Q. AlvesI


Amburana acreana Ducke leaves afforded coumarin, p-hydroxybenzoic, vanillic acids, campesterol 3-β-D-glucoside and amburoside B.

http://dx.doi.org/10.21577/0100-4042.20250010

Publicado online: maio 15, 2024
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Total access: 396

Quim. Nova 2025, 48(1), e‑20250011, 1-8

 

Chemical constituents, antioxidant and antimicrobial activities of Pavonia glazioviana Gurke (Malvaceae)

Micaelly S. OliveiraI; Otemberg S. ChavesII; Yanna C. F. TelesIII; Diégina A. FernandesIV; Camila Macaúbas-SilvaI;
Wallace A. M. QueirozII; Jéssica B. LimaV; Maristela R. R. M. MazzottiV; Edeltrudes O. LimaI,II; Givanildo L. FernandesVI;
Adilva S. ConceiçãoV; Maria de Fátima Vanderlei de SouzaI,II,*


A phytochemical study from aerial parts of Pavonia glazioviana Gurke led to identify fifteen compounds, with emphasis on the polymethoxylated flavonoids that showed antimicrobial activity.

http://dx.doi.org/10.21577/0100-4042.20250011

Publicado online: maio 21, 2024
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Total access: 339

Quim. Nova 2025, 48(1), e-20250014, 1-6

 

Solid-state spectroscopic, thermokinetics and thermal analysis of aceclofenac coordination complexes with lanthanum and gadolinium

Laís D. S. M. K. MeloI; Cláudio T. CarvalhoI; Pedro Enrique Sánchez JiménezII,III; Thiago SequinelI; Antonio PerejónII,III;
Luis Allan Pérez MaquedaII; Tiago A. D. ColmanI,*


The synthesis of the coordination complex between aceclofenac and lanthanum or gadolinium ions results in stable compounds with potential medical and catalytic applications. Thermoanalytical characterization reveals information about the structure and thermal stability, while thermokinetic analysis investigates reaction rates, decomposition, and phase transitions, contributing to an overall understanding of the thermal behavior of the complex.

http://dx.doi.org/10.21577/0100-4042.20250014

Publicado online: maio 24, 2024
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Total access: 298

Quim. Nova 2025, 48(1), e-20250015, 1-8

 

Facile hydrothermal synthesis of niobium pentoxide semiconductor and their application in the photodegradation of dyes and reduction of free fat acids in waste oil

Camilo Aurélio Brandão CrisóstomoI; Fernanda Barbosa DamacenoI; Luele Ribeiro de Sousa BarbosaI; Jânio Santos AlmeidaI; Walker Vinicius Ferreira do Carmo BatistaI; Andréa Renata MalaguttiII; João Paulo de MesquitaIII; Juliana Arriel TorresIV;
Gustavo Duran IgaIV; Caue Ribeiro de OliveiraIV; Roberto Ananias RibeiroV; Henrique A. J. L. MourãoI,VI,*


In this paper, we describe the hydrothermal synthesis of Nb2O5 and their application in photodegradation of dyes (methylene blue (MB) and indigo carmine (IC)) and photoesterification of free fatty acids (FFA) which are present in waste cooking oil (WCO).

http://dx.doi.org/10.21577/0100-4042.20250015

Publicado online: maio 29, 2024
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Quim. Nova 2025, 48(1), e-20250016, 1-11

 

Transacetalization of glycerol with 2,2-dimethoxypropane using zeolites under mild conditions

Paula M. VeigaI; Ayres G. DiasII; Cláudia de O. VelosoI; Cristiane A. HenriquesI,*


HBeta, USY, and HZSM-5 zeolites produce solketal from glycerol and 2,2-DMP with higher yield under mild conditions.

http://dx.doi.org/10.21577/0100-4042.20250016

Publicado online: maio 29, 2024
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Total access: 385

Quim. Nova 2025, 48(1), e-20250018, 1-7

 

Aplicação da espectrometria de massas com ionização por paper spray e método quimiométrico OPLS-DA para o diagnóstico do câncer de próstata pela análise de amostras de urina

Thifanny T. P. da SilvaI; Ademar D. V. MáquinaI,II,*; Anízia F. F. DuransI; Lucas G. da CostaI; Frederico G. PintoIII;
Timothy J. GarrettIV; Waldomiro Borges NetoI


PSI-MS spectra of urine samples from control individuals and patients with prostate cancer used in multivariate calibration with orthogonal correction to develop the OPLS-DA model.

http://dx.doi.org/10.21577/0100-4042.20250018

Publicado online: junho 6, 2024
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Total access: 328

Quim. Nova 2025, 48(1), e-20250065, 1-6

 

Rapid quantitative analysis of methamphetamine by portable near-infrared spectroscopy and pls modeling

Shan LiuI,II,III,IV,#; Yuemeng ChenI,III,#; Fang WangII,*; Jingjie WuIII; Guo TangV,*; Song BaiII,*


A portable near-infrared spectrometer (linear variable filter (LVF) used as a dispersive element) was applied to rapidly detect methamphetamine samples on site, and 359 methamphetamine crystal and 187 methamphetamine tablet samples were modeled and analyzed.

http://dx.doi.org/10.21577/0100-4042.20250065

Publicado online: novembro 5, 2024
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Total access: 127

Quim. Nova 2025, 48(1), e-20250067, 1-12

 

Corrosão localizada do alumínio em meios aerados e em meios com baixo teor oxigênio: estudo e comparação por meio de curvas de polarização

João Victor de S. Araujo*; Aline D. Gabbardo; Stela M. Fernandes; Isolda Costa


In this study, the influence of deaeration on the electrochemical behavior of aluminum was investigated using polarization techniques. The advantages of deaeration in assessing localized corrosion on aluminum are addressed.

http://dx.doi.org/10.21577/0100-4042.20250067

Quim. Nova 2025, 48(1), e-20250068, 1-8

 

Synthesis of Zn-Fe bimetallic ZIFs and study of the photocatalytic nitrogen fixation performance

Fuchen Cao; Feilong Li; Tianping He*


Based on zeolitic imidazolate framework-8 (ZIF-8), Zn-Fe bimetallic ZIF was synthesized. Subsequently, the photocatalytic nitrogen fixation performance of the sample was investigated. The synthesis process of the samples is simple, and they exhibit excellent photocatalytic nitrogen fixation performance.

http://dx.doi.org/10.21577/0100-4042.20250068

Publicado online: novembro 11, 2024
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Total access: 142

Quim. Nova 2025, 48(1), e-20250069, 1-6

 

Análise dos efeitos de corrosão sob chapas de aço-carbono 1020 causadas por aerossol marinho e poluição: um estudo comparativo em chapas expostas ao ambiente e em simulação de dutos subterrâneos

Arthur K. NoceraI; Guilherme S. SouzaI; Mateus B. de AlmeidaI; Matheus S. e SantosI,*; Noemi L. GilI; Thaís CorrêaII


Corrosion rate comparison in millimeters per year between the cities of Cubatão, Praia Grande and São Paulo in the following cases: exposed without anode; exposed with anode; buried without anode; buried with anode.

http://dx.doi.org/10.21577/0100-4042.20250069

Publicado online: novembro 12, 2024
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Total access: 163

Revisão Quim. Nova 2025, 48(1), e-20250002, 1-12

 

Emerging trends of organic electrosynthesis in Brazil

Guilherme M. Martins*; Kleber T. de Oliveira*


This review provides an overview of recent advancements in organic electrosynthesis in Brazil. It highlights the principles, applications, and limitations of various electrosynthetic methodologies, aiming primarily to enhance the understanding of fundamental principles and stimulate research in this field.

http://dx.doi.org/10.21577/0100-4042.20250002

Publicado online: abril 26, 2024
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Total access: 344

Quim. Nova 2025, 48(1), e-20250003, 1-8

 

Transporte mediado por coloides e o seu efeito na dinâmica dos poluentes no solo

Alana Deduck CicilinskiI,*; Vander de Freitas MeloII; Patricio Peralta-ZamoraI


The existence of mobile colloidal fractions favors the transport of pollutants through the soil, even when strongly sorbed.

http://dx.doi.org/10.21577/0100-4042.20250003

Publicado online: abril 26, 2024
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Total access: 324

Educação Quim. Nova 2025, 48(1), e-20250006, 1-7

 

The role of jj coupling on the energy levels of heavy atoms

Lucas A. L. Dias; Thiago M. Cardozo; Roberto B. Faria*


Comparative splitting of spectroscopic terms for a p2 electronic configuration following LS and jj spin-orbit coupling schemes.

http://dx.doi.org/10.21577/0100-4042.20250006

Publicado online: maio 3, 2024
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Total access: 395

Quim. Nova 2025, 48(1), e-20250064, 1-7

 

Conceitos em cristalografia estrutual: uma abordagem compreensiva da lei de Bragg e do fator de estrutura

Rafael P. Machado; Antônio C. Doriguetto*


Integrating the chemical, historical, physical, and mathematical concepts encompassed by crystallography in the determination of crystal structure through X-ray diffraction fosters a more comprehensive and effective grasp of this powerful interdisciplinary tool.

http://dx.doi.org/10.21577/0100-4042.20250064

Publicado online: outubro 31, 2024
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Total access: 177

Assuntos Gerais Quim. Nova 2025, 48(1), e-20250012, 1-11

 

Alfred Schaeffer e suas contribuições para a química

Rodrigo Régis C. SilvaI,II; Rita de Cássia MarquesIII; Carlos A. L. FilgueirasI,*


Alfred Schaeffer (center) in one of his classes for medical and pharmaceutical courses at the Faculty of Medicine of Belo Horizonte in the 1910s.

http://dx.doi.org/10.21577/0100-4042.20250012

Publicado online: maio 21, 2024
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Total access: 311

Quim. Nova 2025, 48(1), e-20250066, 1-10

 

Brief reflections on the 4th Industrial Revolution and its impact in chemical sciences

Ana Paula N. de SouzaI; Gabriel Francisco S. da SilvaI; Bernardo Cardeal DarzéI; André Vinícius D. SenraII; Jaqueline D. SenraI,*


The 4th Industrial Revolution is promoting a paradigm change in the society. Chemistry alignment with the 4.0 scenario requires the involvement of chemists towards some technological challenging themes already in course.

http://dx.doi.org/10.21577/0100-4042.20250066

Publicado online: novembro 6, 2024
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Total access: 138

On-line version ISSN 1678-7064 Printed version ISSN 0100-4042
Química Nova
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