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8:36, dom mar 23

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vol. 39, No. 6, 2016



Artigo de Capa
Quim. Nova 2016, 39(6), 732-740

Sustentabilidade no uso do fósforo: uma questão de segurança hídrica e alimentar

Glaucia Pantano; Guilherme M. Grosseli; Antonio A. Mozeto; Pedro S. Fadini*

Phosphorus is a fundamental nutrient to life on planet, and essential for food production. Currently, the main source of phosphorus to agriculture are fertilizers obtained from phosphate rock, a nonrenewable resource, threatening the global food security.

http://dx.doi.org/10.5935/0100-4042.20160086

Publicado online: maio 10, 2016
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Total access: 4940

Artigo Quim. Nova 2016, 39(6), 647-654

 

Analisis QSAR-2D de los derivados de 1,4-di-N-oxidos de quinoxalina con actividad contra la enfermedad de chagas

Cristian J. Guerra*; Jesús M. López; Said F. Figueredo; Adolfo E. Muñoz; Juana R. Robles


The nucleophilic power of the N-oxide group is related to the biological activity of quinoxaline 1,4 di-N-oxides against T. cruzi.

http://dx.doi.org/10.5935/0100-4042.20160078

Publicado online: maio 6, 2016
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Total access: 1687

Quim. Nova 2016, 39(6), 655-660

 

Propriedades e avaliação catalítica da zeólita x nanométrica contendo cátions metilamônio

Joao G. P. Vicente; Patrícia M. Lima; Dilson Cardoso*


In order to increase accessibility to catalytic sites, studies have been carried out in order to reduce the diameter of the particles of zeolites to the nanometer scale.

http://dx.doi.org/10.5935/0100-4042.20160079

Publicado online: maio 6, 2016
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Total access: 2260

Quim. Nova 2016, 39(6), 661-668

 

Estimativa de vida útil do PBX (plastic-bonded explosive) com envelhecimento acelerado

Edemar KirchhofI,*; Roberta Jachura RochaI; Nanci Miyeko NakamuraII; Camila Maria LapaII; Glaci Ferreira Martins PinheiroII; Rene Francisco Boschi GonçalvesIII; José Atílio Fritz Fidel RoccoI; Koshun IhaI


Optical microscope image through PBX (80 % HMX) cluster with PBLH.

http://dx.doi.org/10.5935/0100-4042.20160072

Publicado online: abril 25, 2016
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Total access: 1914

Quim. Nova 2016, 39(6), 669-675

 

Scope of various solvents and their effects on solvothermal synthesis of Ni-BTC

Farrukh IsrarI; Duk Kyung KimII; Yeongmin KimI; Wongee ChunI,*


This picture depicts the scheme which has been employed in this manuscript for solvothermal synthesis of Ni-BTC. The organic linker H3BTC was dissolved in series of solvents and solvothermally reacted with NiNO3.6H2O(aqueous) for the production of Ni-BTC.

http://dx.doi.org/10.5935/0100-4042.20160068

Publicado online: abril 20, 2016
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Total access: 3500

Quim. Nova 2016, 39(6), 676-685

 

Naturaleza de las interacciones Mδ+∙∙∙δ+C-Oδ- en carbonilos metálicos. Un estudio basado en la topología de la densidad de carga electrónica y su función laplaciana

Gabriel J. Buralli; Darío J. R. Duarte*; Nélida M. Peruchena


The nature of Mδ+···δ+C-Oδ- interactions in metal carbonyls can be explained through the topological analysis of the electron charge density and its Laplacian function within the framework of the Quantum Theory of Atoms in Molecules (QTAIM).

http://dx.doi.org/10.5935/0100-4042.20160080

Publicado online: maio 6, 2016
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Total access: 2186

Quim. Nova 2016, 39(6), 686-690

 

Degradação fotocatalítica de corante utilizando-se nanocompósito TiO2/óxido de grafeno

Arlene B. S. Nossol; Suzamar M. C. Rosa; Edson Nossol; Aldo J. G. Zarbin; Patricio Peralta-Zamora*


Synergetic degradation of organic substrates by TiO2-graphene oxide nanocomposites: electron shuttling and preliminary adsorption of target compounds.

http://dx.doi.org/10.5935/0100-4042.20160081

Publicado online: maio 6, 2016
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Total access: 2638

Quim. Nova 2016, 39(6), 691-696

 

Non-crystalline copper oxide highly dispersed on mesoporous alumina: synthesis, characterization and catalytic activity in glycerol conversion to acetol

Tiago Pinheiro BragaI,*; Nadine EssayemII; Antoninho Valentinic


An excessive increase in surface area was observed after Cu2+ insertion by wet impregnation from β-Al(OH)3 support, which is explained by the redissolution and recrystallization of bayerite to γ-Al2O3 during the impregnation of Cu2+.

http://dx.doi.org/10.5935/0100-4042.20160074

Publicado online: abril 29, 2016
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Total access: 1708

Quim. Nova 2016, 39(6), 697-703

 

Determinação de estanho em amostras ambientais por espectrometria de fluorescência atômica

Daniel L. GarcezI; Amauri A. MenegárioI,*; José R. FerreiraII,III; Warren T. CornsIV; Carlos A. SuárezI; Ana M. C. M. RolisolaI; Lauren N. M. YabukiI


Determination of tin in natural samples collected in area under anthropogenic action through atomic fluorescence spectrometry.

http://dx.doi.org/10.5935/0100-4042.20160073

Publicado online: abril 25, 2016
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Total access: 2009

Quim. Nova 2016, 39(6), 704-711

 

In situ prepared TiO2 nanoparticles cross-linked sulfonated pva membranes with high proton conductivity for DMFC

Jignasa N. Solanki; Preeti S. Mishra; Zagabathuni Venkata Panchakshari Murthy*


Sulfonated poly(vinyl alcohol) (SPVA) membranes and in situ prepared TiO2 nanoparticles incorporated SPVA membranes are prepared to use in direct methanol fuel cell. Very low methanol permeability is observed with the prepared membranes. Proton conductivity of the membranes is higher than Nafion and high thermal stability is achieved with increased TiO2 nanoparticles concentration.

http://dx.doi.org/10.5935/0100-4042.20160076

Publicado online: abril 29, 2016
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Total access: 1969

Quim. Nova 2016, 39(6), 712-719

 

Evaluación de DES, FSC Y SPME/CG-MS para la extracción y determinación de compuestos responsables del aroma de café tostado de vilcabamba - ecuador

Jorge G. FigueroaI,*; Luis F. VargasII


Three extraction methods were compared (SPME, SCF and SDE) for isolation of flavor compounds from roasted ground coffee of Vilcabamba (Ecuador). Identification and characterization of volatile compounds were achieved using gas GC-MS.

http://dx.doi.org/10.5935/0100-4042.20160077

Publicado online: abril 29, 2016
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Total access: 3041

Quim. Nova 2016, 39(6), 720-731

 

A strategy for the rapid identification of fungal metabolites and the discovery of the antiviral activity of pyrenocine A and harzianopyridone

Laura P. IócaI; Stelamar RommingerI,II; Mario F. C. SantosI; Karin F. BandeiraI; Fabiana T. RodriguesI; Miriam H. KossugaI; Karen J. NicacioI; Everton L. F. FerreiraI; Raquel P. Morais-UranoI; Messias S. PassosI; Luciana K. KohnIII; Clarice W. ArnsIV; Lara D. SetteV; Roberto G. S. BerlinckI,*


A strategy for the rapid identification of fungal metabolites.

http://dx.doi.org/10.5935/0100-4042.20160092

Publicado online: maio 26, 2016
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Total access: 2879

Nota Técnica Quim. Nova 2016, 39(6), 741-747

 

Determinação espectrofotométrica de WPNI e HMF em leite UHT através da análise por componentes principais

Leandra N. O. NevesII; Paulo Henrique F. da SilvaI; Marcone A. L. de OliveiraII,*


Spectrophotometric methods associated to chemometric analysis as an attractive approaching to determination of chemical modifications during UHT milk heat treatment assisting in a quality control process.

http://dx.doi.org/10.5935/0100-4042.20160082

Publicado online: maio 6, 2016
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Total access: 1967

Educação Quim. Nova 2016, 39(6), 748-756

 

A educação ambiental na formação de professores de química: estudo diagnóstico e representações sociais

Lailton Passos Cortes JuniorI,*,#; Carmen FernandezII,#


Central words of social representations of environmental education of future teachers of chemistry.

http://dx.doi.org/10.5935/0100-4042.20160044

Publicado online: março 11, 2016
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Total access: 3011

Quim. Nova 2016, 39(6), 757-764

 

Sobre um estudo da entropia de shannon no contexto da mecânica quântica: uma aplicação ao oscilador harmônico livre e confinado

Wallas S. Nascimento*; Frederico V. Prudente


General behavior of the Shannon entropy Sx and Sp depending on the distance of confinement (xc). Highlight that the inflection of the curves is due to the influence of confinement, while the behavior of these for large xc tends toward a free system.

http://dx.doi.org/10.5935/0100-4042.20160045

Publicado online: março 11, 2016
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Total access: 2388

Quim. Nova 2016, 39(6), 765-769

 

Calculation of conditional equilibrium in serial multiple precipitation of metal sulfides with hydrogen sulfide stream generated from sodium sulfide: a didactic tool for chemistry teaching

Renata Bellová; Danica Melicherčíková; Peter Tomčík*


Serial precipitation of Cd2+, Cu2+, Zn2+, Mn2+ and Pb2+ ions forming various colored sulfides in bubblers with chemically generated hydrogen sulfide stream.

http://dx.doi.org/10.5935/0100-4042.20160062

Publicado online: abril 12, 2016
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Total access: 1730

On-line version ISSN 1678-7064 Printed version ISSN 0100-4042
Química Nova
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