JBCS



14:51, sex mar 21

Acesso Aberto/TP



vol. 43, No. 4, 2020



Artigo de Capa
Quim. Nova 2020, 43(4), 447-454

Classificando cédulas brasileiras (R$) usando análise de imagem por smartphone

Bruno V. VittorazziI; Rayana A. CostaII,#; Larissa M. CoelhoIII; Marsele M. IsidoroI; Kássio M. G. LimaIV; Paulo R. FilgueirasII; Wanderson RomãoI,II,V,*

Authenticity of Brazilian banknotes can be evaluated using smartphone application associated with chemometric methods by digital imaging.

http://dx.doi.org/10.21577/0100-4042.20170508

Publicado online: abril 3, 2020
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Total access: 2428

Artigo Quim. Nova 2020, 43(4), 391-398

 

CeαMn1-αO2 catalysts supported over γ-Al2O3 prepared by modified redox-coprecipitation methods for n-hexane combustion

Jesus Rojas QuispeI; Romulo CruzI; Rosario Sun KouII; Gino PicassoI,*


Alumina-supported Ce0.33Mn0.67O2 achieved a total combustion of n-hexane at a lower temperature than did the bulk sample with the same metallic surface density, probably due to the interaction of Ce4+ with Mn4+ species, which led to an active phase with easy reducibility and labile oxygen.

http://dx.doi.org/10.21577/0100-4042.20170507

Publicado online: março 31, 2020
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Quim. Nova 2020, 43(4), 399-403

 

Iridoides, triterpenos e outros constituintes das cascas do caule e flores de Tabebuia caraiba Bignoniaceae

Aloízio de O. SoaresI; Caroline TieppoII; Luzinátia Ramos SoaresIII; Joaquim CorsinoII; Alex Fonseca SouzaII; Fernanda R. GarcezII; Walmir S. GarcezII,*


The phytochemical study of Tabebuia caraiba led to the isolation of triterpenes and iridoids. The chemical profile by HPLC/MS showed the presence of other constituents, however, most of the isolated compounds could not be detected.

http://dx.doi.org/10.21577/0100-4042.20170513

Publicado online: abril 6, 2020
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Quim. Nova 2020, 43(4), 404-412

 

Emissões de poluentes atmosféricos em condições reais de pavimentação asfáltica: material particulado, black carbon e hidrocarbonetos policíclicos aromáticos

Victor P. Piracelli; Ismael R. Amador; Fabio C. Sabino; Jurandir P. Pinto; Carlos R. Silva Jr.; Maria Cristina Solci*


This article access air emissions in two real asphalt paving occasions at the Londrina City. Particulate Matter (PM), Black Carbon (BC) and Polycyclic Aromatic Hydrocarbons (PAHs) are discussed. Health, environment and climate change are related.

http://dx.doi.org/10.21577/0100-4042.20170509

Publicado online: abril 3, 2020
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Total access: 1234

Quim. Nova 2020, 43(4), 413-418

 

Quantification of bergenin, antioxidant activity and nitric oxide inhibition from bark, leaf and twig of Endopleura uchi

Magno P. MunizI,*; Sergio M. NunomuraIII; Emerson S. LimaII; Arleilson S. LimaII; Patrícia D. O. de AlmeidaII; Rita C. S. NunomuraI


Articles available about Endopleura uchi species is mainly address bark studies. For this work, we report the first chemical and biological experiments using the leaf and twig of the species.

http://dx.doi.org/10.21577/0100-4042.20170514

Publicado online: abril 6, 2020
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Quim. Nova 2020, 43(4), 419-425

 

Diversity of the diterpenes in the leaves of Xylopia laevigata (Annonaceae) and their cytotoxicities

Emmanoel V. CostaI,*; Marília F. C. SampaioII; Leociley R. A. MenezesIII; Lívia M. DutraIII,IV; Cinara O. S. CostaV; Maria Lúcia B. PinheiroI; Felipe M. A. da SilvaI; Milena B. P. SoaresV,VI; Daniel P. BezerraV; Andersson BarisonIII; Hector H. F. KoolenVII


Six known terpenes, five diterpenes and one sesquiterpene were isolated from the leaves of Xylopia laevigata (Annonaceae). Additionally, their cytotoxicities were  assessed by the Alamar blue assay. The isolated diterpenes are described here for the first time for X. laevigata.

http://dx.doi.org/10.21577/0100-4042.20170504

Publicado online: março 31, 2020
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Total access: 1642

Quim. Nova 2020, 43(4), 426-434

 

Kinetic parameters study for the slow pyrolysis of coffee residues based on thermogravimetric analysis

Fernando L. TibolaI; Tiago J. P. de OliveiraII; Daniel A. CerqueiraIII,*; Carlos H. AtaídeIV; Cássia R. CardosoV


Kinetic parameters for coffee husks pyrolysis were determined using thermogravimetric analyses and different kinetic models. The presence of six different reactions was identified using the model of parallel and independent reactions. This is the first work using this model for coffee husks pyrolysis.

http://dx.doi.org/10.21577/0100-4042.20170511

Publicado online: abril 6, 2020
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Total access: 1334

Quim. Nova 2020, 43(4), 435-441

 

Optimization of extraction conditions of volatile compounds of roasted beef by solid-phase microextraction

Vanessa C. FranciscoI,*; Larissa C. AlmeidaII; Stanislau Bogusz JuniorII; João Oiano NetoIII; Renata T. NassuIII


The optimized conditions established in this study will help to extract the largest number of volatile compounds in roasted beef.

http://dx.doi.org/10.21577/0100-4042.20170505

Publicado online: março 31, 2020
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Total access: 1235

Quim. Nova 2020, 43(4), 442-446

 

A survey of parabens in commercial baby wipes from Brazil and estimation of daily exposure

Bruno Alves RochaI,II,*; Mariana Zuccherato BocatoI; Elder Francisco LatorracaIII; João Paulo Bianchi XimenezI; Fernando Barbosa Jr.I


High concentrations of parabens were found in Brazilian baby wet wipes.

http://dx.doi.org/10.21577/0100-4042.20170494

Publicado online: março 12, 2020
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Total access: 1597

Quim. Nova 2020, 43(4), 455-462

 

Fatores de emissão de compostos carbonílicos medidos em um túnel do Rio de Janeiro, Brasil, em condições reais de dirigibilidade

Jose Claudino Souza AlmeidaI; Andre Luis do Prado BragaII; Leonardo BastosI; Graciela ArbillaII,*; Eduardo Monteiro MartinsI


Samples were collected in two sites inside Rebouças tunnel to calculate the emission factors of urban vehicles in real conditions.

http://dx.doi.org/10.21577/0100-4042.20170502

Publicado online: março 31, 2020
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Total access: 1357

Revisão Quim. Nova 2020, 43(4), 463-473

 

Imobilização enzimática: conceito e efeitos na proteólise

Izadora L. FurlaniI; Bruno S. AmaralII; Regina V. OliveiraI; Quezia B. CassI,*


Application of immobilized trypsin in different forms and supports for modulation of proteomic assays.

http://dx.doi.org/10.21577/0100-4042.20170525

Publicado online: abril 16, 2020
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Total access: 2792

Nota Técnica Quim. Nova 2020, 43(4), 474-479

 

Determinação de docetaxel e metabólitos em plasma por UPLC-MS/MS: desenvolvimento de metodologia analítica e aplicação clínica

Suziane RaymundoI; Victória Vendramini MüllerI; Mariane TegnerI; Andiara ArtmannI; Natália B. AndriguettiI; Gilberto SchwartsmannII; Rafael LindenI; Marina V. AntunesI,*


A sensitive UPLC-MS/MS method for the determination of Docetaxel and metabolites (M1+M3) in human plasma samples was developed and validated. The method employs a liquid-liquid extraction and a reversed-phase separation with electrospray ionization.

http://dx.doi.org/10.21577/0100-4042.20170498

Publicado online: março 16, 2020
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Total access: 915

Quim. Nova 2020, 43(4), 480-485

 

Construção de equipamento de baixo custo para enrolar filamentos de impressoras 3D

Diego C. de Andrade; Thiago V. B. Ferraz; André L. B. Formiga; Juliano A. Bonacin*


Construction of an accessory coupled to the extruder for winding the filaments of 3D printer.

http://dx.doi.org/10.21577/0100-4042.20170493

Publicado online: março 12, 2020
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Total access: 1474

Educação Quim. Nova 2020, 43(4), 486-492

 

O uso do caso talidomida auxiliando na construção de significados em aulas de Química do Ensino Superior

Leandro Antonio de OliveiraI; Ana Luiza de QuadrosII,*


Pedagogical link-making among chemical concepts and a historical fact involving these concepts can contribute significantly to the engagement of students with the content and, as a result, with knowledge.

http://dx.doi.org/10.21577/0100-4042.20170487

Publicado online: março 5, 2020
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Total access: 1543

Quim. Nova 2020, 43(4), 493-505

 

Desafios e perspectivas atuais na formação do professor de química: expectativas sobre o mestrado profissional em química em Rede Nacional (PROFQUI)

Glaucia R. GonzagaI,II,*; Daniel C. de PaivaII; Marcelo L. EichlerI


The PROFQUI was projected for high school teachers of chemistry. The objectives are to raise difficulties and propose perspectives for chemistry teaching based on the elaboration of innovative educational products for the different school contexts.

http://dx.doi.org/10.21577/0100-4042.20170495

Publicado online: março 12, 2020
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Total access: 1721

Assuntos Gerais Quim. Nova 2020, 43(4), 506-514

 

Radionuclídeos como marcadores de um novo tempo: o Antropoceno

Cleyton Martins da SilvaI,II, Graciela ArbillaI,*, Wilson MachadoIII e Ricardo SoaresIII,IV


Anthropocene: the Atomic Age.

http://dx.doi.org/10.21577/0100-4042.20170503

Publicado online: março 31, 2020
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Quim. Nova 2020, 43(4), 515-519

 

Epidemiologia do esgoto como estratégia para monitoramento comunitário, mapeamento de focos emergentes e elaboração de sistemas de alerta rápido para COVID-19

Fernando F. SodréI,*; Cristina C. S. BrandãoII; Carla S. VizzottoII; Adriano O. MaldanerIII


Wastewater-based epidemiology is an emerging and relatively inexpensive strategy for monitoring contagion curves in near real time and creating early warning systems, especially in regions where clinical trials are scarce

http://dx.doi.org/10.21577/0100-4042.20170545

Publicado online: maio 6, 2020
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Total access: 2111

Errata Quim. Nova 2020, 43(4), 520

 

Errata


http://dx.doi.org/10.21577/0100-4042.20170539

Publicado online: maio 12, 2020
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On-line version ISSN 1678-7064 Printed version ISSN 0100-4042
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