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10:45, qui nov 21

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EDIÇÃO ATUAL vol. 44, No. 10, 2021



Artigo de Capa
Quim. Nova 2021, 44(10), 1328-1352

Microplásticos: ocorrência ambiental e desafios analíticos

Cassiana C. Montagner*; Mariana Amaral Dias; Eduardo Maia Paiva; Cristiane Vidal

Microplastics are considered ubiquitous contaminants in the environment once they are detected in all compartments. Their characterization is a challenge to the environmental chemistry, especially for those smaller than 1 mm.

http://dx.doi.org/10.21577/0100-4042.20170791

Publicado online: junho 29, 2021
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Total access: 4872

Artigo de Contra Capa
Quim. Nova 2021, 44(10), 1252-1260

Biogeoquimica espaço-temporal da liteira em ambiente de floresta natural na Amazônia central

Ananda Gabrielle de Matos RebêloI,*; Maria Terezinha Ferreira MonteiroI; Sávio José Filgueiras FerreiraI; Eduardo Antonio Ríos VillamizarI; Ézio Sargentini JuniorII; Marcos Alexandre BolsonII; Sergio Duvoisin JuniorIII

The chemical elements concentration determination in the litter is one of the parameters for assessing the vegetation quality, contributing to serve as a reference value for Amazon tropical areas.

http://dx.doi.org/10.21577/0100-4042.20170789

Publicado online: junho 29, 2021
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Total access: 1113

Editorial Quim. Nova 2021, 44(10), 1225

 

Boas novidades em Química Nova

Giovanna Machado; Jorge M. David; Nelson H. Morgon


http://dx.doi.org/10.21577/0100-4042.20170835

Editorial

Total access: 581

Artigo Quim. Nova 2021, 44(10), 1226-1235

 

Feasibility of H2 production by acid corrosion using H2SiF6 and waste Fe sources

Tatiane Carvalho MaedaI; Letícia TeixeiraI; Lorrane Cristine CaixetaI; Raissa AntonelliI,II; Camila Ferreira PintoI; Sandra Cristina DantasI; Priscila Pereira SilvaI; Ana Claudia GranatoI; David Maikel FernandesIII; Geoffroy Roger Pointer MalpassI,*


This study investigated the feasibility of H2 production by acid corrosion, employing a by-product from the fertilizer industry (Hexafluorsilic acid - H2SiF6) and waste iron sources. The influence of the variables was evaluated by factorial design, verifying greater production of H2 for materials with higher contact areas.

http://dx.doi.org/10.21577/0100-4042.20170778

Publicado online: junho 16, 2021
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Total access: 1349

Quim. Nova 2021, 44(10), 1236-1244

 

Environmental parameters and relationships with COVID-19 cases in central south america

Thais Costa BrunelliI,*; Sophia PaivaI; Angélica Yara SiqueiraI; Cleyton Elizeu SantanaI; Luís Otávio CurvoI; João Basso MarquesI; Thiago Rangel RodriguesII


We investigated the correlation between COVID-19 and environmental parameters in central South America. Fire radiative power (FRP) influence the daily cases COVID-19. The relative humidity of the air, (U%), mitigated the COVID-19.

http://dx.doi.org/10.21577/0100-4042.20170786

Publicado online: junho 22, 2021
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Total access: 1083

Quim. Nova 2021, 44(10), 1245-1251

 

Electrospinning PBAT (poly (butylene-adipate-co-terephthalate))/PCL (poly(ε-caprolactone) blend containing propolis for the preparation of a smart wound dressing

Heloisa G. ZanellaI; Ariane R. Souza RossinI; Janice Caroline HardtII; Andressa G. RosenbergerII; Juliana C. WiggersII; Josiane CaetanoII; Douglas C. DragunskiI,II,*


Electrospun matrices generated from electrospinning technique. These were incorporated with propolis for utilization in wound dressing.

http://dx.doi.org/10.21577/0100-4042.20170787

Publicado online: junho 22, 2021
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Total access: 1318

Quim. Nova 2021, 44(10), 1261-1267

 

Síntese, caracterização e estudo dos parâmetros de Judd-Ofelt de compostos β-dicetonatos de Eu(III) ou Sm(III)

Maria I. X. ScapolanI; Daniel H. de OliveiraI; Jorge H. S. K. MonteiroII; Marian R. DavolosIII; Renata D. AdatiI,*


The intensity parameters were calculated using absorption and emission spectra of the Sm(III) or Eu(III) beta-diketone complexes, respectively. Highlyintense luminescence from lanthanides compounds enables us to identify the correlationbetween symmetry environment and spectroscopic properties.

http://dx.doi.org/10.21577/0100-4042.20170792

Publicado online: julho 6, 2021
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Total access: 1551

Quim. Nova 2021, 44(10), 1268-1279

 

Síntese de novos 1,2,3-triazóis inspirados no SRPIN340 e avaliação de seus efeitos em linhagem celular de glioblastoma humano

Sara Maria Ribeiro de SousaI; Róbson Ricardo TeixeiraI,*; Adilson Vidal CostaII; Alex Ramos de AguiarI; Victor da Rocha FonsecaIII; Valdemar Lacerda Jr.III; Wanderson RomãoIII; Laser Antônio Machado OliveiraIV; Iára Mariana Lellis RibeiroIV; Katiane de Oliveira Pinto Coelho NogueiraIV; Claudia Jorge do NascimentoV; Jochen JunkerVI


A series of 1,2,3-triazoles inspired on the SRPIN340 was synthesized and had their effects evaluated on human glioblastoma multiform cell line U87MG.

http://dx.doi.org/10.21577/0100-4042.20170793

Publicado online: julho 6, 2021
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Total access: 1246

Revisão Quim. Nova 2021, 44(10), 1280-1299

 

A química por trás dos medicamentos distribuídos pelo programa farmácia popular no Brasil: rotas sintéticas, relação estrutura-atividade e perspectivas futuras

Giovanny C. dos SantosI; Julia L. RodriguesI; Júllia R. de SouzaII; Luiz C. da Silva-FilhoI; Bruno H. S. T. da SilvaII,*


This paper describes the structure, mechanism of action, synthetic routes, among other parameters related to drugs intended to treat the main diseases in Brazil.

http://dx.doi.org/10.21577/0100-4042.20170770

Publicado online: maio 24, 2021
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Total access: 5819

Quim. Nova 2021, 44(10), 1300-1310

 

Alternatives for the production of levulinic acid obtained from biomass

Lucas A. dos SantosI; Gabrielle das V. FragaI; Danilo Aguiar PontesI; Leila M. A. CamposII; Luiz A. M. PontesI,III; Leonardo S. G. TeixeiraIV,*


Levulinic acid is a potential building block for biorefineries to add value to biomass and reduce dependence on the world oil economy.

http://dx.doi.org/10.21577/0100-4042.20170773

Publicado online: junho 4, 2021
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Total access: 1411

Quim. Nova 2021, 44(10), 1311-1327

 

Processamento e aplicação de biomateriais poliméricos: avanços recentes e perspectivas

Marcela Piassi BernardoI; Rafaella Takehara PaschoalinII; Danilo Martins dos SantosI; Stanley BilattoI; Cristiane Sanchez FarinasI; Daniel Souza CorreaI; Osvaldo N. Oliveira Jr.II; Luiz Henrique Capparelli MattosoI,*


This paper examines the recent advances in the design materials for biomedical applications prepared via electrospinning, solution blow spinning, film preparation methods, and 3D printing techniques.

http://dx.doi.org/10.21577/0100-4042.20170781

Publicado online: junho 16, 2021
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Total access: 1775

Nota Técnica Quim. Nova 2021, 44(10), 1353-1359

 

Development and validation of a fast and simple hplc-uv method to determine caffeine in guarana (Paullinia cupana) food supplements

Júlia Cecília Pereira Coura*; Cláudia Aparecida de Oliveira e Silva; Edvane Santos Silva; Sara Araújo Valladão; Maria Gorette Resende Duarte


The proposed method may be used both in health surveillance and monitoring and in quality control of food supplements, especially concerning the confirmation of caffeine content, which must be shown on the labels of products available on the market.

http://dx.doi.org/10.21577/0100-4042.20170774

Publicado online: junho 4, 2021
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Total access: 1296

Quim. Nova 2021, 44(10), 1360-1363

 

Application of water beads as a novel and simple sorbent for smartphone-based colorimetric determination of iron in water

Cristina B. Adamo; Ayandra S. Junger; Dosil P. de Jesus*


Commercially available water beads made of superabsorbent sodium polyacrylate can be a simple and inexpensive sorbent for iron concentration before colorimetric assay using digital images.

http://dx.doi.org/10.21577/0100-4042.20170782

Publicado online: junho 16, 2021
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Total access: 2095

Quim. Nova 2021, 44(10), 1364-1368

 

Sistema de baixo custo para execução e monitoramento on-line de reações fotocatalíticas: aplicação em redução de nitro-fenol

Byanca S. SalvatiI; Sirlon F. BlaskieviczI; Patricia G. CorradiniI,II; Lucia H. MascaroI,*


In this technical note, an impedimetric sensor was built from low-cost materials, to monitor online a reduction reaction of an organic contaminant (4-nitrophenol) to a value-added product (4-amino-phenol).

http://dx.doi.org/10.21577/0100-4042.20170794

Publicado online: julho 6, 2021
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Total access: 1213

Educação Quim. Nova 2021, 44(10), 1369-1378

 

Contribuições à formação de professores de química para atuação em espaço de educação não formal: quadro analítico como facilitador da avaliação

Ariane Baffa Lourenço; Maria Eduarda Vizotto; Salete Linhares Queiroz*


Teacher education in non-formal educational setting: The Scientific and Cultural Dissemination Center case.

http://dx.doi.org/10.21577/0100-4042.20170785

Publicado online: junho 16, 2021
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Total access: 993

Quim. Nova 2021, 44(10), 1379-1387

 

Promover modelos explicativos sobre las interacciones químicas del felodipino-citocromo P450: una propuesta didáctica basada en la modelización

Rafael Amador-RodríguezI,*; Daniel InsuastyII; Maximiliano Méndez-LópezII; Edgar MárquezII


Teaching of chemistry in context and based on modeling favors the construction and reconstruction of student explanatory models.

http://dx.doi.org/10.21577/0100-4042.20170784

Publicado online: junho 16, 2021
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Total access: 1278

Quim. Nova 2021, 44(10), 1388-1391

 

Cartesian axis and plane conventions in Cnv symmetry groups

Lucas A. L Dias; Roberto B Faria*


The water molecule should be placed on the yz plane, but a survey in the literature shows that this recommendation, made by Mulliken in 1955, is not followed in many textbooks and articles. This affects the label of the asymmetric vibration and of the HOMO as B1 or B2.

http://dx.doi.org/10.21577/0100-4042.20170790

Publicado online: junho 29, 2021
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Total access: 1008

Assuntos Gerais Quim. Nova 2021, 44(10), 1392-1394

 

(Des)construindo a metabolômica em produtos naturais: um convite a discussão

Ricardo Moreira Borges*; João Victor Mendes Resende


Should I label this approach I’m following? Should I call it metabolomics to match others? But I’ve just paid more attention to on the statistics.

http://dx.doi.org/10.21577/0100-4042.20170783

Publicado online: junho 16, 2021
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Total access: 1102

Quim. Nova 2021, 44(10), 1395-1403

 

Da fama ao ostracismo: oito reagentes que deixaram o ambiente laboratorial

Jéssica Frontino Paulino; Júlio Carlos Afonso*


An example of replacing an old laboratory procedure (heterogeneous generation of H2S) by a current one (homogeneous generation of H2S).

http://dx.doi.org/10.21577/0100-4042.20170788

Publicado online: junho 22, 2021
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Total access: 1157

On-line version ISSN 1678-7064 Printed version ISSN 0100-4042
Química Nova
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