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6:49, sáb nov 23

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EDIÇÃO ATUAL vol. 43, No. 2, 2020



Artigo de Capa
Quim. Nova 2020, 43(2), 212-225

Abrindo a caixa de pandora dos nanomedicamentos: há realmente muito mais 'espaço lá embaixo'

Alexsandra Conceição Apolinário; Giovanna Cassone Salata; Arthur F. R. Bianco; Claudio Fukumori; Luciana Biagini Lopes*

Nanotechnology applied to the medical, biomedical and pharmaceutical fields have been under investigation for many years, but there are still plenty of possibilities for application to human health.

http://dx.doi.org/10.21577/0100-4042.20170481

Publicado online: fevereiro 20, 2020
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Total access: 3962

Artigo Quim. Nova 2020, 43(2), 133-139

 

Influência da composição dos nanofios Pt-Ir/C na atividade catalítica frente a oxidação eletroquímica de etanol em meio ácido

Gláucia R. O. AlmeidaI,II,#,¶; Eliana M. SussuchiIII; Cristiano T. de MenesesIV; Luiz P. da CostaV,§; Giancarlo R. Salazar-BandaI,II,#,*; Katlin I. B. EguiluzI,II,#


Pt-It/C nanowire catalysts were successfully synthesized with different metallic composition and were all more active towards ethanol oxidation than the commercial Pt/C catalyst, and are promising for application in direct ethanol fuel cells.

http://dx.doi.org/10.21577/0100-4042.20170469

Publicado online: janeiro 22, 2020
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Total access: 1215

Quim. Nova 2020, 43(2), 140-145

 

Conversão fotoeletrocatalítica de CO2 e biogás em produtos de interesse energético utilizando semicondutores nanoestruturados de Ti/TiO2 modificados com óxido de cobre

Laís Bresciani, Letícia Vognach, Carlos Henrique Lagemann; Simone Stülp*


The objective of the work is to modify nanostructured semiconductors of Ti/TiO2 with copper oxide for application in the photoelectrocatalytic conversion of CO2 and biogas in fuel products of energetic interest.

http://dx.doi.org/10.21577/0100-4042.20170463

Publicado online: janeiro 16, 2020
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Total access: 1425

Quim. Nova 2020, 43(2), 146-154

 

Avaliação da biomassa de fungos amazônicos como fonte de lipases para biocatálise

Israel P. RomanoI,*; Vanderlei S. dos SantosII; Ana Carolina de Lima Paes LouzadaIII; Raimundo C. Pereira JuniorIV; Edson J. do CarmoV; Adolfo José da MotaV; Hiléia dos S. BarrosoVI; Ivaldo Itabaiana JuniorVII; José Odair PereiraV; Spartaco Astolfi FilhoV; Sandra Patrícia ZanottoII


Biomass-bound lipases from fungal organisms may exhibit hydrolytic, synthetic and enantioselective activity - useful capabilities for many important applications in biocatalysis.

http://dx.doi.org/10.21577/0100-4042.20170470

Publicado online: fevereiro 3, 2020
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Total access: 1265

Quim. Nova 2020, 43(2), 155-167

 

Análise de amostras de combustíveis por fotometria, nir portátil e RMN de 1H - uma comparação com os resultados encontrados por técnicas normatizadas

Flavia TosatoI; Eliane V. BarrosI; Danyelle A. CunhaI; Francine D. SantosI; Thayná CorrêaII; Amanda NunesII; Izabella JastrowII; Mylena A. SilverolII; Layla U. PinheiroII; Alessandro C. SeabraII; Paulo R. FilgueirasI,*; Álvaro C. NetoI; Leandro WangIII,IV; Ernesto C. FerreiraI; Wanderson RomãoI,II,V,#


Samples of gasoline, ethanol and diesel were collected at gas stations at ES state and analyzed by portable NIR, 1H NMR and photometry in order to verify the efficiency of the techniques in detect adulteration.

http://dx.doi.org/10.21577/0100-4042.20170473

Publicado online: fevereiro 5, 2020
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Total access: 2734

Quim. Nova 2020, 43(2), 168-174

 

Reuse of collagen and hydroxyapatite from the waste processing of fish to produce polyethylene composites

Túlio P. BoaventuraI,*; Anderson M. PeresII; Viviane S. B. GilII; Camila S. B. GilII; Rodrigo L. OréficeII; Ronald K. LuzI


Reuse of waste from the processing of fish to produce composite artifacts.

http://dx.doi.org/10.21577/0100-4042.20170475

Publicado online: fevereiro 10, 2020
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Total access: 1235

Quim. Nova 2020, 43(2), 175-180

 

Otimização e validação de método baseado em QuEChERS para determinação de conservantes em cosméticos por HPLC-DAD

Rafael A. Gonçalves; Noemi Nagata; Patricio G. Peralta-Zamora*


Analytical method based in QuEChERS was optimized and validated to be used for analysis of real cosmetic samples. The results showed that QuEChERS can be used for determination of some preservatives in cosmetic matrix.

http://dx.doi.org/10.21577/0100-4042.20170471

Publicado online: fevereiro 3, 2020
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Total access: 1817

Quim. Nova 2020, 43(2), 181-187

 

Chemical constituents of Sinningia mauroana and screening of its extracts for antimicrobial, antioxidant and cytotoxic activities

Vanessa WiniewskiI; Alessandra F. SerainII; Eduardo L. de SáI; Marcos J. SalvadorII; Maria Élida A. StefanelloI,*


Phytochemical study of aerial parts from Sinningia mauroana (Gesneriaceae) yielded 17 known compounds, which are been reported for the first time in the species. Additionally, the antimicrobial, antioxidant and cytotoxic activities of its extracts were investigated.

http://dx.doi.org/10.21577/0100-4042.20170478

Publicado online: fevereiro 17, 2020
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Total access: 1262

Quim. Nova 2020, 43(2), 188-193

 

Judd-Ofelt analysis of Tb3+ and upconversion study in Yb3+-Tb3+ co-doped CaLiBO glasses

Idelma A. A. TerraI; Luis J. Borrero-GonzálezII,*; Juliana M. P. AlmeidaI; Antonio C. HernandesI; Luiz A. O. NunesI,#


We report on the study of the spectroscopic properties in Ytterbium-Terbium (Yb3+-Tb3+) co-doped calcium lithium borate (CaLiBO) glasses, with the study's focus being on the upconversion process. Our results showed that a cooperative energy transfer (CET) from two Yb3+ ions to one Tb3+ ion is the origin of the Tb3+ upconversion luminescence in the visible region.

http://dx.doi.org/10.21577/0100-4042.20170465

Publicado online: janeiro 22, 2020
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Total access: 1365

Quim. Nova 2020, 43(2), 194-200

 

Síntese e caracterização de nitrosil complexos com ação antibacteriana frente a Pseudomonas aeruginosa

Thuanny M. de Sousa; Dayana P. S. Penha; Daniel de L. Pontes; Ana C. F. de B. Pontes; Francisco O. N. da Silva*


Nitrosyl ruthenium complexes containing 2,2'-bipyridine and phen = 1,10'-phenanthroline ligands presented antibacterial action against Pseudomonas aeruginosa.

http://dx.doi.org/10.21577/0100-4042.20170476

Publicado online: fevereiro 10, 2020
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Total access: 1864

Quim. Nova 2020, 43(2), 201-205

 

Chemical variability of Allamanda cathartica L. flowers assessed by multivariate data analysis

Deivisson W. Rodrigues; Ana Flavia F. Muller; Tiago J. Bonomini; Luiz C. Klein-Júnior; Ruth M. Lucinda-Silva; Angela Malheiros*


Allamanda cathartica L. flowers were collected in different locations in the state of Santa Catarina, Brazil. Extractive solutions were analyzed by HPLC-PDA. In order to investigate the similarity of the samples, PCA and HCA analysis were performed.

http://dx.doi.org/10.21577/0100-4042.20170467

Publicado online: janeiro 21, 2020
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Total access: 1618

Quim. Nova 2020, 43(2), 206-211

 

Complexo estuarino lagunar mundaú-manguaba: caracterização da matéria orgânica natural e interação com íons Hg2+

Alinne Diana Pinho WanderleyI; Andre Gustavo Ribeiro MendonçaI; Luciana Camargo de OliveiraII; Isis Martins FigueiredoI; Andrea Pires FernandesI; Luan Tavares BatalhaI; Wander Gustavo BoteroI,*


The natural organic matter of the waters of the lagoon estuarine complex Mundau-Manguaba presented high affinity with Hg2+ ions and humification/aromaticity dependent on the characteristics of lagoons.

http://dx.doi.org/10.21577/0100-4042.20170489

Publicado online: março 5, 2020
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Total access: 1153

Nota Técnica Quim. Nova 2020, 43(2), 226-230

 

Particle size distribution applied to milk powder rehydration

Júlia d'Almeida FrancisquiniI; Evandro MartinsI; Isis Rodrigues Toledo RenheII; Luiz Fernando Cappa de OliveiraIII,*; Rodrigo StephaniIII; Ítalo Tuler PerroneIV; Antônio Fernandes de CarvalhoI


Whole powder milks were analyzed by scanning electron microscopy and particle size analysis. By statistical analysis a more modern rehydration index was developed as a complement to the technique that is usually used to determine powders rehydration.

http://dx.doi.org/10.21577/0100-4042.20170466

Publicado online: janeiro 21, 2020
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Total access: 1179

Educação Quim. Nova 2020, 43(2), 231-238

 

Extratos de Lilium sp., Agapanthus sp. e Hydrangea sp.: comportamento como indicadores naturais em diferentes faixas de pH

Jhulli M. da Silva; Renata de C. Martins; Fabiele Bernardi; Camila de M. R. dos Santos; Keller P. Nicolini; Jaqueline Nicolini*


An experimental propose using flowers extracts: The picture shows the flowers used to extract the dyes in presence of H+ and OH- ions (indicating the tests done in aqueous solutions).

http://dx.doi.org/10.21577/0100-4042.20170459

Publicado online: janeiro 10, 2020
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Total access: 1558

Quim. Nova 2020, 43(2), 239-248

 

Influência da frequência e participação no desempenho em um ambiente de aprendizagem centrado no aluno

Camila Aparecida Tolentino CicutoI,*; Bayardo Baptista TorresII


Organizational representation of study periods and discussion groups. Students: white circles; teacher: black circle and monitor: gray circle.

http://dx.doi.org/10.21577/0100-4042.20170464

Publicado online: janeiro 16, 2020
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Total access: 1098

Assuntos Gerais Quim. Nova 2020, 43(2), 249-252

 

Só erra quem faz, e quem faz erra! um manifesto pelo cálculo da propagação de incertezas

Luís Moreira Gonçalves


The equation of propagation of uncertainty is a simple and powerful equation that chemists should apply wisely and more often.

http://dx.doi.org/10.21577/0100-4042.20170460

Publicado online: janeiro 14, 2020
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Total access: 1920

On-line version ISSN 1678-7064 Printed version ISSN 0100-4042
Química Nova
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