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EDIÇÃO ATUAL vol. 43, No. 9, 2020



Artigo de Capa
Quim. Nova 2020, 43(9), 1294-1311

Isoflavonoides da tribo dalbergieae: uma contribuição quimiossistemática para a subfamília papilionoideae

Adonias A. CarvalhoI,II; Lucivania R. dos SantosI; Jurema S. de FreitasI; Mariana H. ChavesI,*

This review describes a total of 240 isoflavonoids reported in 69 species and 15 genera from the Dalbergieae tribe. Formononetin, biochanin A and medicarpin were more frequent in this tribe and the antimicrobial, estrogenic, cytotoxic and antioxidant were predominant biological activities.

http://dx.doi.org/10.21577/0100-4042.20170588

Publicado online: julho 8, 2020
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Total access: 2318

Artigo Quim. Nova 2020, 43(9), 1205-1209

 

Study of spectrophotometric characteristics of the charge transfer complex of taurine drug with 7,7,8,8-tetracyanoquinodimethane

Fang Tian; Sheng Yun Li*


The formation of the charge transfer complex was also confirmed by both infrared and 1H NMR measurements. The thermodynamic quantities of the complex were estimated. A new spectrophotometric method was developed for the determination of taurine.

http://dx.doi.org/10.21577/0100-4042.20170637

Publicado online: setembro 15, 2020
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Total access: 1192

Quim. Nova 2020, 43(9), 1210-1215

 

Evaluation of the relative protection factor of rosemary extract in biodiesel in the presence of transition metal ions

Kelly R. SpacinoI; Hágata CremascoI; Karina B. AngilelliI; Ana Carolina G. MantovaniII; Dionisio BorsatoI,*


The relative protection factor (RPF) of rosemary extract in biodiesel was studied in the presence of metallic ions. The phenolic compounds present in rosemary extract protected the biodiesel and Co2+ and Fe2+ ions led to the degradation.

http://dx.doi.org/10.21577/0100-4042.20170610

Publicado online: agosto 10, 2020
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Total access: 836

Quim. Nova 2020, 43(9), 1216-1219

 

Chemical composition of biological active extracts of Tapirira guianensis (Anacardiaceae)

Eliezer P. da SilvaI,II,#; Jorge M. DavidII,*; Juceni P. DavidIII; Geisse H. Trindade GarciaIII; Maisa T. SilvaII


Flowers and seeds of Tapirira guianensis Aubl. (Anacardiaceae) afforded new bioactive alkenyl dihydrobenzofuranoids besides known compounds. Unsaturated fatty acids are predominant in seed's oil.

http://dx.doi.org/10.21577/0100-4042.20170605

Publicado online: agosto 7, 2020
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Total access: 1058

Quim. Nova 2020, 43(9), 1220-1226

 

In situ DRIFTS/MS studies on the interaction of methanol and ethyl acetate over Mg-La catalyst

Adão S. GonçalvesI,II; Cristiane A. HenriquesI,II,*; Deborah V. CesarII


Ethyl acetate and methanol adsorb on the Mg-La catalyst surface forming intermediates that are identified by the combination of DRIFTS and MS techniques. The intermediates reaction products suggest that a mechanism of Eley-Rideal predominates in the reaction catalyzed by Mg-La.

http://dx.doi.org/10.21577/0100-4042.20170603

Publicado online: agosto 3, 2020
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Total access: 1727

Quim. Nova 2020, 43(9), 1227-1233

 

Volatile compounds in cachaças obtained from three sugarcane varieties cultivated under the managements: organic, conventional and without fertilization

João Henrique do Nascimento e SilvaI,*; Marta Regina Verruma-BernardiI; André Eduardo de Souza BellucoI; Simone Daniela Sartorio de MedeirosII; Alessandra Lopes de OliveiraIII


The volatile compounds found in cachaça can come from the raw material used in the production of the drink, during the fermentation process, distillation or aging in wooden barrels, providing essential aromas and flavors for quality cachaça.

http://dx.doi.org/10.21577/0100-4042.20170606

Publicado online: agosto 7, 2020
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Total access: 785

Quim. Nova 2020, 43(9), 1234-1239

 

Improving the catalytic features of the lipase from Rhizomucor miehei immobilized on chitosan-based hybrid matrices by altering the chemical activation conditions

Elizabete Araújo CarneiroI; Ana Karine Pessoa BastosII; Ulisses Marcondes Freire de OliveiraIII; Leonardo José Brandão Lima de MatosIV; Wellington Sabino AdrianoV; Rodolpho Ramilton de Castro MonteiroIII; José Cleiton Sousa dos SantosIII,VI,*; Luciana Rocha Barros GonçalvesIII


In this study, we aimed to tune the catalytic features of the lipase from Rhizomucor miehei immobilized on chitosan hybrids beads by altering the chemical activation conditions of the support.

http://dx.doi.org/10.21577/0100-4042.20170615

Publicado online: agosto 21, 2020
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Total access: 875

Quim. Nova 2020, 43(9), 1240-1245

 

Otimização do processo não invasivo e não destrutivo de extração e análise de metabólitos voláteis de mamão papaia por SPME-GC-MS

Larissa Rocha TerraI,II; Marcia Miguel Castro FerreiraI; Daniel TeraoII; Sonia Claudia do Nascimento de QueirozII,*


The non-destructive and non-invasive extraction process of papaya's VOCs by SPME was optimized using an experimental design. The variables conditioning time and fiber exposure time were evaluated. The optimal conditions were found by analyzing the response surface.

http://dx.doi.org/10.21577/0100-4042.20170611

Publicado online: agosto 10, 2020
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Total access: 859

Quim. Nova 2020, 43(9), 1246-1250

 

Oxidative stability and cold filter plugging point of biodiesel blends derived from fats and soy oil

João V. BraunI,II; Samuel J. SantosI,II; Guilherme C. EspíndolaI; Gabriel F. de MattosI; Diego P. OngarattoI; Diogo M. de OliveiraI,II; Marlon W. da SilvaI; Vinícius VendrusculoI; Vinícius O. B. dos SantosI,II; Rodrigo E. RennerII; Fabrício F. NaciukI,II; Marcelo V. MarquesI,II; Luiz A. M. FontouraI,II,*


Oxidative stability and the cold filter plugging point of biodiesel blends made from fats and soy oil in different proportions were evaluated.

http://dx.doi.org/10.21577/0100-4042.20170619

Publicado online: agosto 21, 2020
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Total access: 852

Quim. Nova 2020, 43(9), 1251-1257

 

Aspectos estruturais de esferas de quitosana/PVA reticuladas com glutaraldeído submetidas a diferentes tratamentos térmicos

Thamy G. P. SobreiraI,III; Lindomar A. da SilvaII; Frederico D. de MenezesII; Elvis J. FrançaIII; Kátia Aparecida da Silva AquinoI,*


The chitosan extracted from chitin, present in insects, fungi, and arthropods is cross-linked in order to obtain chitosan spheres. The novel physical characteristics obtained are applicable in several areas.

http://dx.doi.org/10.21577/0100-4042.20170613

Publicado online: agosto 20, 2020
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Total access: 994

Quim. Nova 2020, 43(9), 1258-1263

 

Estudos de QSAR para SARS-COV-2

Clodoaldo MachadoI; Keller P. NicoliniII; Jaqueline NicoliniII,*


Drug screening combined with the use of mathematical models has been shown to be an important strategy for predicting the susceptibility of microorganisms to drugs.

http://dx.doi.org/10.21577/0100-4042.20170600

Publicado online: agosto 3, 2020
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Total access: 1351

Revisão Quim. Nova 2020, 43(9), 1264-1276

 

Nanocristais de perovskitas coloidais: histórico, propriedades e aplicações

Caroline de Mayrinck; André Felipe Vale da Fonseca; Marco Antônio Schiavon*


The perovskite nanocrystals have emerged as a new class of promising materials in optoelectronics, due to their high photoluminescent quantum yield, short decay times and narrow emissions bands that covers the entire visible spectrum mainly by the composition control.

http://dx.doi.org/10.21577/0100-4042.20170597

Publicado online: julho 23, 2020
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Total access: 1935

Quim. Nova 2020, 43(9), 1277-1293

 

Enriquecimento elementar por meio de cultivo: plantas e cogumelos

Aline P. Oliveira; Juliana Naozuka*


The success of the elemental enrichment of foods depends on chemical speciation studies and allows to supply macro and microelements deficiencies.

http://dx.doi.org/10.21577/0100-4042.20170601

Publicado online: agosto 3, 2020
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Total access: 1399

Nota Técnica Quim. Nova 2020, 43(9), 1312-1319

 

Construção de um suporte ajustável lab-made impresso em 3D para medição de ângulo de contato

Vinicius A. O. P. da SilvaI; Vinicius A. P. TartareI; Cristiane KalinkeII; Paulo Roberto de OliveiraI; Daniel Cardoso de SouzaI; Juliano A. BonacinII,*; Bruno C. JanegitzI,*


The construction of a lab-made contact angle measuring device by using 3D-printing technology.

http://dx.doi.org/10.21577/0100-4042.20170624

Publicado online: agosto 31, 2020
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Total access: 1942

Educação Quim. Nova 2020, 43(9), 1320-1325

 

Extração assistida por ultrassom para determinação de lipídeos em alimentos: um experimento de laboratório

Bruno L. FerreiraI; Junior V. BeikII; Salvino J. Z. AlvesIII; Flavia A. HenriqueII; Elenise SauerIV; Cesar A. ChornobaiIV; Simone BowlesII; Eduardo S. ChavesIII,*


An easy and efficient laboratory experiment designed for undergraduate students by using ultrasound assisted extraction for subsequent determination of total lipids in food samples.

http://dx.doi.org/10.21577/0100-4042.20170592

Publicado online: julho 15, 2020
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Total access: 1685

Quim. Nova 2020, 43(9), 1326-1332

 

Extração do paracetamol e análise da dispersão da massa de comprimidos: comparando medicamentos genérico e de referência em laboratório de ensino

Lourenço Luis Botelho de SantanaI,II,#; Orlando Maia BarbozaII; Fernando Alves BarrettoI; Wilson Araujo LopesI,III; Silvio CunhaI,III,*


A new undergraduate experiment was developed based on the comparison of generics and brand name drug. Extraction of paracetamol and tablet mass checking with statistic considerations were also addressed, simulating quality control.

http://dx.doi.org/10.21577/0100-4042.20170596

Publicado online: julho 23, 2020
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Total access: 1891

Quim. Nova 2020, 43(9), 1333-1343

 

Argumentação em aulas de química: estratégias de ensino em destaque

Ariane Baffa Lourenço; Salete Linhares Queiroz*


Are we ready for argumentation in chemistry classrooms? An investigation into pre-service teachers' readiness for promoting argumentation.

http://dx.doi.org/10.21577/0100-4042.20170594

Publicado online: julho 21, 2020
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Total access: 1016

Quim. Nova 2020, 43(9), 1344-1349

 

Resgate da reação de Debus-Radziszewski: ensino prático de reações multicomponentes na síntese da lofina

Victória Laysna dos Anjos Santos; Arlan de Assis Gonsalves; Cleônia Roberta Melo Araújo*


Practical didactic sequence using the Debus-Radziszewski reaction to teach multicomponent reactions.

http://dx.doi.org/10.21577/0100-4042.20170608

Publicado online: agosto 7, 2020
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Total access: 1907

Assuntos Gerais Quim. Nova 2020, 43(9), 1350-1361

 

A história da ciência como "remédio" no ensino de química: episódio - estudo sobre a invenção da teoria atômico-molecular moderna

César de B. Lobato*


This article brings up the Dalton - Gay-Lussac - Avogadro debate, which took place in the early 19th century. Such a discussion allowed the assumption of gaseous diatomic molecules. The original figure from the Dalton's paper was modified by the author, with the intent of representing the conceptual change that the Dalton's Theory underwent.

http://dx.doi.org/10.21577/0100-4042.20170595

Publicado online: julho 21, 2020
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Total access: 1136

Quim. Nova 2020, 43(9), 1362-1373

 

Alquimia experimental

Pedro Augusto F. Borges; Louise Vasconcelos Groener; Gabriel Pereira Gomes; Joanna P. Rodrigues; Geraldo Magela de Lima; Wagner N. Mussel; Rodinei Augusti; Carlos A. L. Filgueiras*


Alchemical "gold": tin samples before and after treatment with calcium polysulfide. The gold colour is due to a coating of mosaic gold, or stannic sulfide

http://dx.doi.org/10.21577/0100-4042.20170604

Publicado online: agosto 6, 2020
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Total access: 2088

On-line version ISSN 1678-7064 Printed version ISSN 0100-4042
Química Nova
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