Eldevan S. SilvaI,II,III; Rafael C. MarchiIII; Carla Sthefane P. MatosII; Maria Fátima G. F. SilvaIII; João B. FernandesIII; Odair C. BuenoIV; Rose M. CarlosIII,*
Physical chemical characterization of the magnesium (II) complex containing isovanillic acid with insecticidal and fungicidal potential against leaf-cutting ant and its symbiotic fungus.
Andréia O. RodriguesI; Rômulo S. AngélicaI; Simone P.A. PazI,II,*
Infrared spectroscopy proved to be an effective technique in the cationic differentiation of bentonites using the characteristic bands "7072 cm-1" and "3620 and 3430 cm-1". The increasing order of intensity follows a pattern characteristic: Na+<Mg+2<Ca+2.
José Alberto Paris JuniorI; Maurício CavicchioliII,*; Rachel Temperani Amaral MachadoIII; Fernando Rogério PavanIII; Douglas Hideki NakahataIV; Pedro Paulo CorbiIV; Adão Marcos Ferreira CostaV; Douglas Henrique PereiraV; Antonio Carlos MassabniI
A silver(I) complex with the antimycobacterial drug isoniazid is described. It presented a minimal inhibitory concentration (MIC90) of 0.78 µg mL-1 against the standard Mycobacterium tuberculosis strain H37Rv.
Vanessa WiniewskiI; Adson S. SilvaI; Kattleen D. C. AlvarezII; Eduardo L. de SáI; Marcos J. SalvadorII; Maria Élida A. StefanelloI,*
Two new and three known naphthoquinones, including three with antioxidant capacity, were isolated of Sinningia reitzii from Santa Catarina State, Brazil.
Fernanda MarderI; Daniela Mueller de LaraI,II; André JasperIII; Eduardo Miranda EthurI; Dieter UhlIV; Simone StülpI,*
The aim of this study is to simulate atmospheric conditions during the formation of charcoal through the carbonization of Araucaria columnaris wood in varying oxygen concentrations.
Jianye LiI,II,#; Youjun YanII,*; Guangjin SunII,III; Jianwei YangII; Zhixiao WangII; Xue YanII
Pt/TiO2 nanoparticles were prepared by a simple two-step aqueous solution method, which consists of a low temperature hydrothermal step and a photoreduction deposition step with Ti(SO4)2 CO(NH2)2 and H2PtCl6 as raw materials.
Lucas V. B. L. Pugnal; Emanuele F. Pissinati; Karina S. Quaglio; Márcio W. Paixão*
This review aims to present the potential of 4CzIPN as a metal-free photocatalyst by highlighting its application in many methodologies recently reported.
Valmir B. Silva; Elisa S. Orth*
Imidazole presents a remarkable catalytic acid, basic and nucleophilic activity, which are explored in several scaffolds: molecular, (bio)materials, polymers and enzymes.
Andressa Priscila GomesI; Eduardo BarbosaI; Ana Laura Anibaletto dos SantosI; Lilian Feltraco LizotI; Elisa SauerII; Solange Cristina GarciaII; Rafael LindenI; Marina Venzon AntunesI; Mariele Feiffer CharaoI,*
A LC-MS/MS method validation using an efficient one-step liquid-liquid extraction, conferring a cost-effective sample analysis and easy execution, making this an applicable biomarker in the laboratory routine.
Fernanda S. C. Soares; Rúbia E. C. R. Rodrigues; Carla M. Bossu*; Márcio S. Soares; Sidney X. dos Santos; Gabriel O. Uebe; Alex A. Silva
Automatic titrometric method in flow-batch with potentiometric detection developed in this work allow the implementation of practical disciplines, such as potentiometric titration and flow analysis system in undergraduate chemistry courses.
Orbitals in general chemistry, Part II: mathematical realities
Guy LamoureuxI,II,*; John F. OgilvieI,III,IV
This article provides mathematical facts about the use of orbitals in General Chemistry; 1) There are four sets of distinct, but equivalent, orbitals; 2) There is no logical basis to explain molecular structure with orbitals.
Guy LamoureuxI,II,*; John F. OgilvieI,III,IV
What are the consequences of teaching the complexity of orbitals to an average student of General Chemistry?
Claudio A. G. da Camara
Polarimetric analysis of chiral chemical substances with the use of polarizing and analyzing filters and the detection of the displacement of polarized light by a photodiode connected to a voltmeter.
Luciana G. MonteiroI; Antonio C. O. GuerraII; Joaquim F. M. SilvaI,*
The learning progression models of Chemistry, Chemical Engineering and Pharmacy students from two federal universities in Rio de Janeiro on Chemical Kinetics were built from Rasch analysis of their responses to a questionnaire based on teachers' conceptions about their learnings.
Leonardo C. Messina; Álvaro T. Omori*
An expeditious, organic solvent-free synthesis of 1,3-diaryltriazenes from substituted anilines using vinegar as solvent / acid source is presented. Reagent reactivity and product stability discussions are suitable for undergraduated students.
Elimar Pires VasconcellosI; Priscila Maria Teixeira Gonçalves de SouzaII; Marcella Rocha FrancoII; Vinícius Gomide de CastroII; Lorena Viana SouzaII; Rochel Montero LagoIII; Marcelo Gomes SpezialiIV,*
The scaleup process can be divided into 3 steps in the lab from the basic research, product, process validation up to the more complex 4th step of building and operating the pilot plant.
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