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EDIÇÃO ATUAL vol. 44, No. 3, 2021



Artigo de Capa
Quim. Nova 2021, 44(3), 267-271

Insecticidal and fungicidal activity of a magnesium compound containing isovanillic acid against leaf-cutting ant and its symbiotic fungus

Eldevan S. SilvaI,II,III; Rafael C. MarchiIII; Carla Sthefane P. MatosII; Maria Fátima G. F. SilvaIII; João B. FernandesIII; Odair C. BuenoIV; Rose M. CarlosIII,*

Physical chemical characterization of the magnesium (II) complex containing isovanillic acid with insecticidal and fungicidal potential against leaf-cutting ant and its symbiotic fungus.

http://dx.doi.org/10.21577/0100-4042.20170693

Publicado online: dezembro 15, 2020
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Total access: 1463

Artigo de Contra Capa
Quim. Nova 2021, 44(3), 272-277

Diferenciação catiônica de bentonitas por infravermelho: um estudo dos efeitos da hidratação dos cátions trocáveis

Andréia O. RodriguesI; Rômulo S. AngélicaI; Simone P.A. PazI,II,*

Infrared spectroscopy proved to be an effective technique in the cationic differentiation of bentonites using the characteristic bands "7072 cm-1" and "3620 and 3430 cm-1". The increasing order of intensity follows a pattern characteristic: Na+<Mg+2<Ca+2.

http://dx.doi.org/10.21577/0100-4042.20170705

Publicado online: janeiro 20, 2021
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Total access: 1348

Artigo Quim. Nova 2021, 44(3), 278-283

 

Synthesis, characterization, dft modeling and in vitro antimycobacterial activity assays of a silver(i)-isoniazid complex

José Alberto Paris JuniorI; Maurício CavicchioliII,*; Rachel Temperani Amaral MachadoIII; Fernando Rogério PavanIII; Douglas Hideki NakahataIV; Pedro Paulo CorbiIV; Adão Marcos Ferreira CostaV; Douglas Henrique PereiraV; Antonio Carlos MassabniI


A silver(I) complex with the antimycobacterial drug isoniazid is described. It presented a minimal inhibitory concentration (MIC90) of 0.78 µg mL-1 against the standard Mycobacterium tuberculosis strain H37Rv.

http://dx.doi.org/10.21577/0100-4042.20170681

Publicado online: dezembro 1, 2020
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Total access: 1118

Quim. Nova 2021, 44(3), 284-287

 

Antioxidant naphthoquinones of Sinningia reitzii from Santa Catarina state, Brazil

Vanessa WiniewskiI; Adson S. SilvaI; Kattleen D. C. AlvarezII; Eduardo L. de SáI; Marcos J. SalvadorII; Maria Élida A. StefanelloI,*


Two new and three known naphthoquinones, including three with antioxidant capacity, were isolated of Sinningia reitzii from Santa Catarina State, Brazil.

http://dx.doi.org/10.21577/0100-4042.20170682

Publicado online: dezembro 1, 2020
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Total access: 870

Quim. Nova 2021, 44(3), 288-294

 

Avaliação química de lenhos carbonizados de Araucaria columnaris sob diferentes concentrações de oxigênio como comparativo de análise de charcoal fóssil

Fernanda MarderI; Daniela Mueller de LaraI,II; André JasperIII; Eduardo Miranda EthurI; Dieter UhlIV; Simone StülpI,*


The aim of this study is to simulate atmospheric conditions during the formation of charcoal through the carbonization of Araucaria columnaris wood in varying oxygen concentrations.

http://dx.doi.org/10.21577/0100-4042.20170689

Publicado online: dezembro 10, 2020
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Total access: 1111

Quim. Nova 2021, 44(3), 295-300

 

Photodegradation of RhB under visible light by Pt/Tio2 nanoparticles prepared through photoreductive deposition process

Jianye LiI,II,#; Youjun YanII,*; Guangjin SunII,III; Jianwei YangII; Zhixiao WangII; Xue YanII


Pt/TiO2 nanoparticles were prepared by a simple two-step aqueous solution method, which consists of a low temperature hydrothermal step and a photoreduction deposition step with Ti(SO4)2 CO(NH2)2 and H2PtCl6 as raw materials.

http://dx.doi.org/10.21577/0100-4042.20170685

Publicado online: dezembro 8, 2020
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Total access: 1130

Revisão Quim. Nova 2021, 44(3), 301-317

 

Recentes aplicações do organofotocatalisador 1,2,3,5-tetraquis(carbazol-9-il)-4,6-dicianobenzeno em transformações químicas

Lucas V. B. L. Pugnal; Emanuele F. Pissinati; Karina S. Quaglio; Márcio W. Paixão*


This review aims to present the potential of 4CzIPN as a metal-free photocatalyst by highlighting its application in many methodologies recently reported.

http://dx.doi.org/10.21577/0100-4042.20170674

Publicado online: novembro 18, 2020
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Total access: 1030

Quim. Nova 2021, 44(3), 318-333

 

Imidazol e catálise: um par perfeito

Valmir B. Silva; Elisa S. Orth*


Imidazole presents a remarkable catalytic acid, basic and nucleophilic activity, which are explored in several scaffolds: molecular, (bio)materials, polymers and enzymes.

http://dx.doi.org/10.21577/0100-4042.20170659

Publicado online: outubro 28, 2020
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Total access: 2181

Nota Técnica Quim. Nova 2021, 44(3), 334-340

 

A simple and sensitive LC-MS/MS method for the determination of S-phenylmercapturic acid in human urine

Andressa Priscila GomesI; Eduardo BarbosaI; Ana Laura Anibaletto dos SantosI; Lilian Feltraco LizotI; Elisa SauerII; Solange Cristina GarciaII; Rafael LindenI; Marina Venzon AntunesI; Mariele Feiffer CharaoI,*


A LC-MS/MS method validation using an efficient one-step liquid-liquid extraction, conferring a cost-effective sample analysis and easy execution, making this an applicable biomarker in the laboratory routine.

http://dx.doi.org/10.21577/0100-4042.20170651

Publicado online: outubro 8, 2020
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Total access: 717

Quim. Nova 2021, 44(3), 341-347

 

Titulador automático em fluxo-batelada utilizando um hardware de código fonte aberto arduino

Fernanda S. C. Soares; Rúbia E. C. R. Rodrigues; Carla M. Bossu*; Márcio S. Soares; Sidney X. dos Santos; Gabriel O. Uebe; Alex A. Silva


Automatic titrometric method in flow-batch with potentiometric detection developed in this work allow the implementation of practical disciplines, such as potentiometric titration and flow analysis system in undergraduate chemistry courses.

http://dx.doi.org/10.21577/0100-4042.20170671

Publicado online: novembro 11, 2020
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Total access: 871

Educação Quim. Nova 2021, 44(3), 348-354

 

Orbitals in general chemistry, Part II: mathematical realities

Guy LamoureuxI,II,*; John F. OgilvieI,III,IV


This article provides mathematical facts about the use of orbitals in General Chemistry; 1) There are four sets of distinct, but equivalent, orbitals; 2) There is no logical basis to explain molecular structure with orbitals.

http://dx.doi.org/10.21577/0100-4042.20170664

Publicado online: outubro 29, 2020
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Total access: 724

Quim. Nova 2021, 44(3), 355-360

 

Orbitals in general chemistry, Part III: consequences for teaching

Guy LamoureuxI,II,*; John F. OgilvieI,III,IV


What are the consequences of teaching the complexity of orbitals to an average student of General Chemistry?

http://dx.doi.org/10.21577/0100-4042.20170660

Publicado online: outubro 28, 2020
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Total access: 711

Quim. Nova 2021, 44(3), 361-365

 

Construction of a low-cost polarimeter for educational purposes

Claudio A. G. da Camara


Polarimetric analysis of chiral chemical substances with the use of polarizing and analyzing filters and the detection of the displacement of polarized light by a photodiode connected to a voltmeter.

http://dx.doi.org/10.21577/0100-4042.20170661

Publicado online: outubro 28, 2020
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Total access: 650

Quim. Nova 2021, 44(3), 366-371

 

Estudo e validação de uma progressão de aprendizagem em cinética química de estudantes de nível superior

Luciana G. MonteiroI; Antonio C. O. GuerraII; Joaquim F. M. SilvaI,*


The learning progression models of Chemistry, Chemical Engineering and Pharmacy students from two federal universities in Rio de Janeiro on Chemical Kinetics were built from Rasch analysis of their responses to a questionnaire based on teachers' conceptions about their learnings.

http://dx.doi.org/10.21577/0100-4042.20170647

Publicado online: setembro 30, 2020
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Total access: 836

Quim. Nova 2021, 44(3), 372-376

 

Síntese verde de 1,3-diariltriazenos simétricos e assimétricos em vinagre

Leonardo C. Messina; Álvaro T. Omori*


An expeditious, organic solvent-free synthesis of 1,3-diaryltriazenes from substituted anilines using vinegar as solvent / acid source is presented. Reagent reactivity and product stability discussions are suitable for undergraduated students.

http://dx.doi.org/10.21577/0100-4042.20170655

Publicado online: outubro 15, 2020
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Total access: 1015

Assuntos Gerais Quim. Nova 2021, 44(3), 377-384

 

Escalonamento de tecnologias: desenvolvimento de produto e processo do laboratório à escala piloto conectado ao mercado (parte 1)

Elimar Pires VasconcellosI; Priscila Maria Teixeira Gonçalves de SouzaII; Marcella Rocha FrancoII; Vinícius Gomide de CastroII; Lorena Viana SouzaII; Rochel Montero LagoIII; Marcelo Gomes SpezialiIV,*


The scaleup process can be divided into 3 steps in the lab from the basic research, product, process validation up to the more complex 4th step of building and operating the pilot plant.

http://dx.doi.org/10.21577/0100-4042.20170665

Publicado online: outubro 29, 2020
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Total access: 1169

On-line version ISSN 1678-7064 Printed version ISSN 0100-4042
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