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EDIÇÃO ATUAL vol. 41, No. 5, 2018



Artigo de Capa
Quim. Nova 2018, 41(5), 567-576

Biogenic synthesis of important environmental minerals: magnesium phosphate compounds and perspectives

Nelson DuránI,*; Wagner J. FavaroII,#

Bacteria, fungi, yeast and Trypanosome biomineralizations play a critical role in biogeochemical cycles. These processes have important technological and environmental applications. This review shows the recent progress in biogenic magnesium phosphate compound.

http://dx.doi.org/10.21577/0100-4042.20170204

Publicado online: fevereiro 22, 2018
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Total access: 2414

Quim. Nova 2018, 41(5), 587-593

Explaining the geometry of simple molecules using molecular orbital energy-level diagrams built by using symmetry principles

Sérgio P. Machado; Roberto B. Faria*

Qualitative energy-level molecular diagrams for different geometry allow to explain the preferred geometry of simple molecules on basis of the number of nonbonding electrons.

http://dx.doi.org/10.21577/0100-4042.20170198

Publicado online: fevereiro 8, 2018
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Total access: 3345

Artigo Quim. Nova 2018, 41(5), 485-491

 

Chemical compositions and antioxidant and antimicrobial activities of propolis produced by Frieseomelitta longipes and Apis mellifera bees

Edineide Cristina A. de SouzaI; Etyene Janyne G. da SilvaI; Hayron Kalil C. CordeiroII; Nauara M. Lage FilhoII; Felipe M. A. da SilvaIII; Diany Lucy S. dos ReisIV; Carla PortoIV; Eduardo J. PilauIV; Luiz Antonio M. A. da CostaI; Afonso D. L. de SouzaIII; Cristiano MenezesV; Adriana FlachI,*,


Chemical compositions of the propolis of Apis mellifera and Frieseomelitta longipes and determination of their biological activities.

http://dx.doi.org/10.21577/0100-4042.20170208

Publicado online: fevereiro 28, 2018
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Total access: 2997

Quim. Nova 2018, 41(5), 492-496

 

Thermogravimetric approach for assessing the oxidation level of a biodiesel sample

Luis Díaz-BalloteI,*; Karen Gómez-HernándezI; Elsy T. Vega-LizamaI; Miguel A. Ruiz-GómezI; Luis MaldonadoI; Emanuel HernándezII


Samples of biodiesel were first exposed to an accelerated oxidation process and then thermally decomposed. The final mass measured on the weight loss curve was used for assessing its oxidative level.

http://dx.doi.org/10.21577/0100-4042.20170199

Publicado online: fevereiro 8, 2018
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Total access: 2080

Quim. Nova 2018, 41(5), 497-506

 

Síntese e avaliação da atividade citotóxica de derivados do eugenol contendo núcleos 1,2,3-triazólicos

Poliana Aparecida Rodrigues GazollaI; Róbson Ricardo TeixeiraI,*; Adalberto Manoel da SilvaII; Boniek Gontijo VazIII; Géssica Adriana VasconcelosIII; Raoni Pais SiqueiraIV; Victor Hugo Sousa GonçalvesIV; Higor Sette PereiraIV; Gustavo Costa BressanIV


Triazolic derivatives of eugenol were prepared and had their cytotoxicity evaluated.

http://dx.doi.org/10.21577/0100-4042.20170206

Publicado online: fevereiro 22, 2018
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Total access: 3012

Quim. Nova 2018, 41(5), 507-511

 

Reactive molecular dynamics simulation and chemical kinetic evaluation of combustion of triethylaluminium (tea)

Rene F. B. Gonçalves; Koshun Iha; José A. F. F. Rocco*


Potential energy variation for triethylaluminum combustion under different temperatures in NVE-MD simulations.

http://dx.doi.org/10.21577/0100-4042.20170200

Publicado online: fevereiro 22, 2018
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Total access: 1347

Quim. Nova 2018, 41(5), 512-518

 

Avaliação da adsorção e estudo eletroquímico de células solares produzidas com TiO2 e corante extraído do Hibiscus

Gidea T. Tractz; Guilherme A. R. Maia; Bianca V. Dias; Franciely Ignachewski; Paulo R. P. Rodrigues*


Dye sensitized solar cell (DSSC) can be prepared with natural dyes, such as Hibiscus. Photovoltaic parameters and a model capable of predicting the adsorption mechanism of the dye on the TiO2 surface are investigated in this paper.

http://dx.doi.org/10.21577/0100-4042.20170212

Publicado online: março 8, 2018
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Total access: 1983

Quim. Nova 2018, 41(5), 519-527

 

Óxido de ítrio e alumínio dopado com Yb3+ e Er3+ incorporado em membrana de poliamida

Michel L. de SouzaI; Susane B. MoscardiniI; Emerson H. de FariaI; Katia J. CiuffiI; Lucas A. RochaI; Eduardo J. NassarI,*; Jorge V. L. SilvaII; Marcelo F. OliveiraII; Izaque A. MaiaII


The article describes the incorporation of the yttrium aluminum oxide doped with Yb3+ and Er3+ incorporated into polyamide membrane obtained by Additive Manufacture. This work presents potential applications to transform infrared radiation into visible, upconversion.

http://dx.doi.org/10.21577/0100-4042.20170201

Publicado online: fevereiro 22, 2018
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Total access: 1472

Quim. Nova 2018, 41(5), 528-532

 

Self-assembly and host-guest behaviors of a supramolecular helicate FeII2L3

Xiao-Huan Fu, Wen-Yuan Wu *; Peng Jiang; Zhen-Yu Han; Rong Wan#


A novel helicate [Fe2L3]4+ resulted from the subcomponent self-assembly of a C3-symmetric triamine, iron(II) and 2-formylpyridine. The supramolecular studies showed that the size, functional group and symmetry of guest molecules remarkably influenced the host-guest interaction patterns.

http://dx.doi.org/10.21577/0100-4042.20170217

Publicado online: março 21, 2018
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Total access: 2598

Quim. Nova 2018, 41(5), 533-539

 

Como obter nanopartículas de ouro usando suco de limão?

Mariana F. Coura; Guilherme Arroyos; Lilian Cherubin Correia; Regina C. G. Frem*


This work shows the use of lemon varieties as natural reducing agents for the preparation of gold nanoparticles from two different metallic precursors. UV-Vis spectra of the red colloidal solutions show bands at ~ 520 nm corresponding to particle sizes of 5-25 nm.

http://dx.doi.org/10.21577/0100-4042.20170202

Publicado online: fevereiro 22, 2018
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Total access: 3332

Quim. Nova 2018, 41(5), 540-543

 

New alkyl phenols and fatty acid profile from oils of pulped Spondias mombin L. seed wastes

Larissa C. de RezendeI,III; Patricia de A. SantosI; Valéria B. RiattoI; Jorge M. DavidI,*; Juceni P. DavidII


Waste seed oils of Spondias mombin presents mostly unsaturated fatty acid, phytosteroids and two new alkenyl phenols.

http://dx.doi.org/10.21577/0100-4042.20170203

Publicado online: fevereiro 22, 2018
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Total access: 1770

Quim. Nova 2018, 41(5), 544-549

 

Preparação, caracterização físico-química e liberação controlada de micropartículas de galactomanana contendo alantoína

Hilana B. M. FrotaI; Jane Eire S. A. MenezesI; Sônia Maria C. SiqueiraI; Nágila Maria P. RicardoII; Tamara G. AraújoIII; Carlos Alberto G. SouzaIV; Paulo N. BandeiraV; Hélcio S. dos SantosV,*


Allantoin was encapsulated with galactomannan extruded from Delonyx regia.

http://dx.doi.org/10.21577/0100-4042.20170214

Publicado online: março 8, 2018
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Total access: 2226

Revisão Quim. Nova 2018, 41(5), 550-566

 

O-glicosídeos 2,3-insaturados: aplicações, rearranjo de ferrier e reações

Aldiceia Luiz de Moura; Lidiane Macedo Alves de Lima; Giselle Barbosa Bezerra; Jucleiton J. R. de Freitas; Mônica Freire Belian; Clécio Souza Ramos; Rodrigo André Avelino; Joao R. de Freitas Filho*


This review summarizes recent developments, in the last twenty years, about the Ferrier rearrangement reaction involving synthesis, mechanistic proposal and application of 2,3-unsaturated O-glycosides.

http://dx.doi.org/10.21577/0100-4042.20170209

Publicado online: fevereiro 28, 2018
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Total access: 2083

Nota Técnica Quim. Nova 2018, 41(5), 577-580

 

Métodos ambientalmente amigáveis para a iodação regiosseletiva da 3,7,3',4'-tetrametoxi-quercetina

Ingrid T. L. Ramos; Telma M. G. da Silva; Tania M. S. da Silva; Celso A. Camara*


Environmental friendly methods for regioselective iodination of the 3,7,3',4'-tetramethoxy-quercetin. Neat reation and aprotic polar solvent selective C-6, protic polar solvent selective C-8 and excess iodine reagent selective di-iodination.

http://dx.doi.org/10.21577/0100-4042.20170205

Publicado online: fevereiro 22, 2018
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Total access: 2378

Quim. Nova 2018, 41(5), 581-586

 

Lixiviação ácida de baterias íon-lítio

Rafael Gundim SilvaI; Júlio Carlos AfonsoII,*; Claudio Fernando MahlerI


Leaching of spent lithium-ion batteries under mild experimental conditions using weak and strong acids. Co(II) was extracted by D2EHPA at pH ~5. Lithium salts can be directly precipitated from the raffinate.

http://dx.doi.org/10.21577/0100-4042.20170207

Publicado online: fevereiro 22, 2018
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Total access: 2149

Educação Quim. Nova 2018, 41(5), 594-599

 

Um estudo termodinâmico da corrosão dos aços carbono pelo sulfeto de hidrogênio - explorando conceitos de equilíbrio químico

Mariana Cristina de Oliveira; Alexandre Pereira de Lima; Rodrigo Monzon Figueredo; Heloisa Andréa Acciari*; Eduardo Norberto Codaro


Schematic representation of possible reaction pathways in the corrosion of carbon steel by hydrogen sulfide.

http://dx.doi.org/10.21577/0100-4042.20170186

Publicado online: janeiro 18, 2018
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Total access: 2728

On-line version ISSN 1678-7064 Printed version ISSN 0100-4042
Química Nova
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