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EDIÇÃO ATUAL vol. 47, No. 9, 2024



Editorial Quim. Nova 2024, 47(9), e-20240076, 1

 

SUSTENTABILIDADE E QUÍMICA AMBIENTAL

Cassiana C. MontagnerI; Giovanna MachadoII; Marco Tadeu GrassiIII


http://dx.doi.org/10.21577/0100-4042.20240076

Editorial

Total access: 265

Artigo Quim. Nova 2024, 47(9), e-20240051, 1-9

 

Multiresidue and multiclass determination of Current-use Pesticides (CUPs) in water samples BY SPE and UHPLC-MS/MS

Állisson A. da S. Avellar; Gabriel A. B. Prates; Larissa da S. Alves; Osmar D. Prestes; Martha B. Adaime; Renato Zanella*


A multiresidue and multiclass method was developed for the determination of current-use pesticides (CUPs) in water samples using solid phase extraction (SPE) with polymeric sorbent and ultra-high performance liquid chromatography with tandem mass spectrometry (UHPLC-MS/MS).

http://dx.doi.org/10.21577/0100-4042.20240051

Publicado online: julho 2, 2024
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Quim. Nova 2024, 47(9), e-20240052, 1-8

 

Efficient and reusable materials with pyrochlore structure for removing red dye from aqueous media

Valber E. S. FirminoI; Júlia B. R. FernandesI; Marcelo J. B. SouzaII; Anne M. Garrido PedrosaI,*


Efficient and reusable adsorbents with pyrochlore structure can be synthesized by a simple route and applied to remove pollutants from aqueous media.

http://dx.doi.org/10.21577/0100-4042.20240052

Publicado online: julho 24, 2024
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Total access: 384

Quim. Nova 2024, 47(9), e-20240053, 1-8

 

Occurrence of polybrominated diphenyl ethers (PBDEs) in surface sediments of an urban artificial lake in Brazil

Fernando F. SodréI,*; Daniel Luiz R. AnnunciaçãoII; Fernanda V. AlmeidaII


Investigation of polybrominated diphenyl ethers (PBDE) levels in Paranoá Lake sediments revealed higher concentrations attributed to effluent discharges from wastewater treatment plants and storm drainage water systems.

http://dx.doi.org/10.21577/0100-4042.20240053

Publicado online: agosto 1, 2024
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Quim. Nova 2024, 47(9), e-20240054, 1-7

 

Métricas da química analítica verde na avaliação de método ecológico para determinação de defensivos agrícolas por CLAE-DAD

Larissa P. dos SantosI; Bárbara E. A. de MagalhãesII; Walter N. L. dos SantosI,II; Luciana B. OliveiraIII; Madson de G. PereiraI; Débora de A. SantanaI,*


The use of ethanol as a mobile phase allowed good chromatographic separation with excellent evaluation by Green Analytical Chemistry metrics.

http://dx.doi.org/10.21577/0100-4042.20240054

Publicado online: agosto 12, 2024
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Total access: 363

Quim. Nova 2024, 47(9), e-20240056, 1-10

 

Photocatalytic water splitting using the semiconductor heterojunction between MoO3-X/CDS

Felipe L. N. SousaI; Luana B. C. OliveiraI,II; Lizeth Carolina MojicaI; Leonardo J. L. MacielI; Wellington de Souza FerreiraI,II;
Denilson V. FreitasI; Marco A. S. GarciaIII; Walter M. AzevedoII; Giovanna MachadoI,*


From gamma irradiation of molybdenum oxide, reduced oxides (MoO3-x) were obtained with expansion of the absorption spectral region. With the heterojunction formation between MoO3-x and cadmium sulfide (CdS) quantum dots, better efficiencies for photocatalytic generation of hydrogen and oxygen are achieved.

http://dx.doi.org/10.21577/0100-4042.20240056

Publicado online: agosto 23, 2024
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Quim. Nova 2024, 47(9), e-20240057, 1-10

 

Validação de método analítico para quantificação dos estrógenos naturais (E1, E2 e E3) e sintético (EE2) em água superficial e material particulado em suspensão de um estuário subtropical do Atlântico Sul, Brasil

Pedro Toledo NettoI,*; Marcos Canto MachadoII; Luiz Laureno Mafra JúniorI; César C. MartinsIII


Here, we present the validation items studied and the distribution of the estrogen 17α-ethinyl estradiol in suspended particulate matter along a salinity gradient in Guaratuba Bay, South Atlantic, Brazil, during summer and winter.

http://dx.doi.org/10.21577/0100-4042.20240057

Publicado online: agosto 28, 2024
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Total access: 325

Quim. Nova 2024, 47(9), e-20240059, 1-9

 

Emprego de dispositivos de difusão em filmes finos por gradiente de concentração (DGT) preparados com agarose, um hidrogel ambientalmente amigável, na avaliação da labilidade de cádmio, cobre e cromo em águas naturais

Karine Andréa Costa; Bruna de Fátima Pereira Schmite; Renata Martins da Silva; Vanessa Egéa dos Anjos*


Homemade diffusive gradients in thin films (DGT) devices prepared with agarose (non-toxic hydrogel) to evaluate the lability of metallic species in Cará-Cará River, Ponta Grossa, Paraná, Brazil.

http://dx.doi.org/10.21577/0100-4042.20240059

Publicado online: setembro 13, 2024
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Total access: 242

Quim. Nova 2024, 47(9), e-20240073, 1-8

 

Efficient removal of norfloxacin from water by Fe-MOFs

Fuhua Wei; Qinhui Ren; Nannan Wang; Hongliang Chen; Yutao Zhang; Zhao Liang


The Fe-MOFs (metal-organic frameworks) were synthesized via a heat of solution method using ferrous sulfate heptahydrate metal ions and 2,5-dihydroxyterephthalic acid as the organic linker. Subsequently, these Fe-MOFs were employed for norfloxacin elimination.

http://dx.doi.org/10.21577/0100-4042.20240073

Publicado online: outubro 25, 2024
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Total access: 182

Quim. Nova 2024, 47(9), e-20240075, 1-11

 

Bioadsorventes de resíduos da agroindústria utilizados na remoção de CD(II)

Adailza Oliveira CarneiroI; Daniel Salustiano Costa NetoI; Cleia Teixeira Santos de FrancaII; Alexilda Oliveira de SouzaII;
Tereza Simonne Mascarenhas SantosI,*


Bioadsorbents prepared from agro-industrial waste were used to remove cadmium(II) with efficiency of 95.7, 92.4 and 60.2%, for BSG (guava seed bioadsorbent), BSC (yellow mombin seed bioadsorbent) and BSM (mango seed bioadsorbent), respectively.

http://dx.doi.org/10.21577/0100-4042.20240075

Publicado online: outubro 25, 2024
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Total access: 227

Quim. Nova 2024, 47(9), e-20240078, 1-6

 

Ecotoxicidade de cremes dentais dessensibilizantes e clareadores em indicadores aquático e terrestre

Maria Thais S. de MacêdoI; Gabrieli Duarte FariasI; Alexandre Almeida-JúniorII; Andressa F. B. de OliveiraIII;
Ana Maria Barros Chaves PereiraIII; Fábio C. SampaioII; Isabela A. P. FariasIV,*


Ten different toothpastes were selected. Toothpaste slurries were prepared at a ratio of 1:2, 1:3, 1:10 and 1:30 (w/w). The immobility/mortality test was carried out on Artemia salina L. The root growth test was carried out on Allium cepa L. pH of the slurries were determined.

http://dx.doi.org/10.21577/0100-4042.20240078

Publicado online: outubro 30, 2024
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Total access: 156

Educação Quim. Nova 2024, 47(9), e-20240048, 1-4

 

Mechanochemistry applied to the synthesis of 2-phenylimidazo[1,2-α]pyridine as a teaching tool for green chemistry

José S. S. Neto; Leonardo Victor E. Guimarães; Filipe T. Coelho; Luciano M. Lião*; Felipe L. Coelho*


Green chemistry principles are introduced to undergraduate students as an experimental class applying mechanochemistry to prepare both 2-bromoacetophenone and 2-phenylimidazo[1,2-α]pyridine through manual grinding and vortex mixing.

http://dx.doi.org/10.21577/0100-4042.20240048

Publicado online: maio 9, 2024
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Total access: 426

Quim. Nova 2024, 47(9), e-20240050, 1-12

 

Educação química para um futuro sustentável: desvendando a cinética química da pirólise do resíduo da cultura de pimenta-do-reino (Piper Nigrum L.) para a potencial produção de bio-óleo

Gyovana L. Welsing; Bruna M. Damm; Maria F. F. Lelis*; Marta A. MachadoI; Paulo R. G. Moura


Biomass is a promising raw material for energy generation and is relevant to be used in chemistry education by enabling the discussion about sustainable development goals (SDGs). For higher education, it is recommended that planning and execution be based on problematized experimental activity (PEA).

http://dx.doi.org/10.21577/0100-4042.20240050

Publicado online: julho 2, 2024
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Quim. Nova 2024, 47(9), e-20240055, 1-5

 

Síntese sustentável do ácido L-piroglutâmico: experimento integrado de síntese orgânica e estereoquímica

Fernando Alves BarrettoI; Leonardo AntonelliI; Silvio CunhaI,II,*


(S)-Pyroglutamic acid solvent-free synthesis in undergraduate experimental classes to reinforce sustainable preparation and understanding of properties of chiral compounds in the solid state.

http://dx.doi.org/10.21577/0100-4042.20240055

Publicado online: agosto 16, 2024
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Quim. Nova 2024, 47(9), e-20240058, 1-10

 

Sustentabilidade e ODS nas páginas: uma análise de conteúdo dos livros didáticos do PNLD 2021 no contexto da química

Iasmyn P. SilvaI; Kleber M. L. FerreiraII; Paula S. PintoI; Tamyris T. da CunhaII,*


Qualitative research employing Bardin's content analysis methodology: this study delves into the approach of Sustainability and Sustainable Development Goals (SDGs) in textbooks of Natural Science area, specifically within Chemistry context.

http://dx.doi.org/10.21577/0100-4042.20240058

Publicado online: setembro 10, 2024
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Total access: 232

Assuntos Gerais Quim. Nova 2024, 47(9), e-20240049, 1-6

 

Sustainability, sustainable development, sustainable chemistry, and green chemistry: parallels and interconnections

Acacio S. de Souza*; Patricia G. Ferreira; Iva S. de Jesus; Alcione S. de Carvalho; Debora O. Futuro; Vitor F. Ferreira*


Sustainability, sustainable development, sustainable chemistry and green chemistry are very close and closely interconnected topics, but they present very different concepts.

http://dx.doi.org/10.21577/0100-4042.20240049

Publicado online: junho 28, 2024
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Total access: 380

On-line version ISSN 1678-7064 Printed version ISSN 0100-4042
Química Nova
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