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EDIÇÃO ATUAL vol. 40, No. 5, 2017



Artigo de Capa
Quim. Nova 2017, 40(5), 534-540

Novos híbridos baseados em oxihidróxido de ferro(III) e nanopartículas de ouro (AuNPs/FeOOH) como catalisadores para a redução de poluentes orgânicos ambientais

Camila Kauany da Silva Azevedo1; Eduardo Arizono dos Reis1; José Carlos Germino2; Jéferson Aparecido Moreto3; Ailton José Terezo1; Fernando Júnior Quites1,*,#

A new δ-FeOOH supported nano-Au catalyst was prepared and employed as catalyst for reduction from 4-nitrophenol to 4-aminophenol. The catalysts exhibited significantly high catalytic activitu for hydrogenation of nitrophenols at room temperature.

http://dx.doi.org/10.21577/0100-4042.20170046

Publicado online: abril 24, 2017
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Total access: 3195

Artigo Quim. Nova 2017, 40(5), 483-490

 

HPLC-DAD profile of phenolic compounds, cytotoxicity, antioxidant and anti-inflammatory activities of the amazon fruit Caryocar villosum

Klenicy K. L. Yamaguchi1; Carlos Vitor Lamarao1; Elenn S. P. Aranha2; Rodrigo Otávio S. Souza2; Patrícia Danielle A. Oliveira2; Marne C. Vasconcellos2; Emerson S. Lima2; Valdir F. Veiga-Junior1,*


Extracts from the Amazon fruit piquiá (Caryocar villosum) were analyzed by HPLC-DAD, gallic and ellagic acids were detected and quantified. Cytotoxicity, antioxidant and anti-inflammatory activities were also studied.

http://dx.doi.org/10.21577/0100-4042.20170028

Publicado online: março 24, 2017
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Total access: 1950

Quim. Nova 2017, 40(5), 491-495

 

The symmetry breaking phenomenon in 1,2,3-trioxolene and C2Y3Z2 (Z= O, S, Se, Te, Z= H, F) compounds: a pseudo Jahn-Teller origin study

Ali Reza Ilkhani*


Quantum-chemical simulations of 1,2,3-Trioxolene which is an intermediate in the acetylene ozonolysis reaction showed that, five member ring of the molecule is unstable in its C2v high-symmetry planar configuration and it is folded along b1 nuclear displacement to Cs symmetry equilibrium geometry.

http://dx.doi.org/10.21577/0100-4042.20170029

Publicado online: março 24, 2017
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Total access: 1488

Quim. Nova 2017, 40(5), 496-505

 

Avaliação da liberação de elementos traço em solos tratados com xisto retortado

Jeniffer V. dos Santos1; Rafael J. B. De Presbiteris1; Vanessa C. G. dos Santos1; Marco T. Grassi1; Iara Messerschmidt1; Betânia F. Pereira1; Rosane Martinazzo2; Gilberto Abate1,*


Retorted oil shale has several trace elements in their composition and these can undergo different processes in the soil: leaching, sorption/desorption, precipitation/solubilization, according to local conditions.

http://dx.doi.org/10.21577/0100-4042.20170030

Publicado online: março 24, 2017
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Total access: 2203

Quim. Nova 2017, 40(5), 506-512

 

Selective synthesis of PEG-monoester using cesium heteropoly acid as heterogeneous catalyst

Fatimah Zahara Abdullah1,*; Azman Ma'amor2; Nur Atiqah Daud1; Sharifah Bee Abd Hamid1


Outline of the research studies to produce PEG-monooleate.

http://dx.doi.org/10.21577/0100-4042.20170040

Publicado online: abril 5, 2017
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Total access: 2575

Quim. Nova 2017, 40(5), 513-522

 

Índices de poder electrofílico global y local para el estudio teórico de la reactividad química: aplicación a derivados carbonilo α,β-insaturados

Said F. Figueredo1,*; Manuel S. Páez1; Francisco Torres2,3


In this study, the electrophilic power and nucleophilic power were proposed as global descriptors for chemical reactivity.

http://dx.doi.org/10.21577/0100-4042.20170031

Publicado online: março 24, 2017
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Total access: 1551

Quim. Nova 2017, 40(5), 523-527

 

Avaliação da produção de hidrogênio a partir da codigestão anaeróbia de resíduos sólidos orgânicos e glicerol residual da produção de biodiesel

Fabrícia M. S. Silva1,#,*; Luciano B. Oliveira2; Claudio F. Mahler1,#; Joao P. Bassin1,++


Biological hydrogen production by anaerobic co-fermentation of organic waste and glycerol is an interesting alternative for clean fuel production.

http://dx.doi.org/10.21577/0100-4042.20170041

Publicado online: abril 5, 2017
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Total access: 2106

Quim. Nova 2017, 40(5), 528-533

 

Óxidos metálicos derivados de materiais tipo hidrotalcitas contendo Ga3+ como catalisadores para síntese de biodiesel etílico

Marcelo Mancini1; Adonis Coelho1; Olavo M. Perrone1; Joao C. Thomeo2; Mauricio Boscolo1,*


Production of ethyl biodiesel by transesterification of soybean oil and ethanol catalyzed by using metal oxides derivatives from like-hydrotalcites materials modified with Ga3+

http://dx.doi.org/10.21577/0100-4042.20170038

Publicado online: março 29, 2017
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Total access: 3035

Quim. Nova 2017, 40(5), 541-547

 

Síntese enzimática do caprilato de isopentila utilizando óleo fúsel como matéria-prima

Renata N. Vilas Bôas; Francisco C. Biaggio*; Domingos S. Giordani; Heizir F. de Castro


The fusel oil consisting primarily of isopentanol (> 60 %), a byproduct generated in the ethanol production, can be served as an alcohol source to yield flavor esters using different organic acids. The concept of a natural ester made by enzymatic synthesis with lipase and natural substrate components is an alternative to conventional organic synthesis route.

http://dx.doi.org/10.21577/0100-4042.20170032

Publicado online: março 24, 2017
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Total access: 2377

Quim. Nova 2017, 40(5), 548-553

 

Contribuição química para o plano de gerenciamento de águas residuais de serviços de saúde

Ingrid Fiedler da Costa Machado1; Juliana Schultz1; Patricio Peralta Zamora1; Antônio S. Mangrich1,2,*


In this work is described an inventory of the main lines of health care wastewater at the Hospital of the Federal University of Paraná (HC/UFPR) and it is proposed a viable wastewater treatment.

http://dx.doi.org/10.21577/0100-4042.20170045

Publicado online: abril 13, 2017
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Total access: 2038

Quim. Nova 2017, 40(5), 554-560

 

Modificação química da pectina do melão caipira (Cucumis melo var. Acidulus)

André L. N. de Sousa1,++; Ana C. B. Ribeiro1,++; Denilton G. Santos1,++; Nadja M. P. S. Ricardo1,++; Maria E. N. P. Ribeiro1,++,*; Eveline S. B. Cavalcanti1,++,2; Arcelina P. Cunha1,++; Nágila M. P. S. Ricardo1,++,#


Pectin extraction of melon is an alternative to increase the profits of producers by having more specific application, adding value to the fruit.

http://dx.doi.org/10.21577/0100-4042.20170042

Publicado online: abril 5, 2017
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Total access: 2405

Revisão Quim. Nova 2017, 40(5), 561-571

 

Estratégias e materiais utilizados em fotocatálise heterogênea para geração de hidrogênio através da fotólise da água

Fabielle C. Marques1; Alexandre M. Stumbo2; Maria C. Canela2,*,#


H2 generation using photocatalysis by irradiation of semiconductor. Photolysis of water without the use of an external potential is known as Water Splitting.

http://dx.doi.org/10.21577/0100-4042.20170015

Publicado online: fevereiro 10, 2017
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Total access: 4519

Quim. Nova 2017, 40(5), 572-585

 

Potenciais alvos moleculares para o desenvolvimento de novos fármacos antituberculose

Guilherme Felipe dos Santos Fernandes1,2; Chung Man Chin2; Jean Leandro dos Santos1,2,*


Different cellular pathways in the Mycobacterium tuberculosis with potential molecular targets useful for drug discovery and development.

http://dx.doi.org/10.21577/0100-4042.20170016

Publicado online: fevereiro 10, 2017
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Total access: 2643

Nota Técnica Quim. Nova 2017, 40(5), 586-593

 

Validação de método por MEFS-HS/CG-EM para determinação de carbaril em plasma sanguíneo

Francisco Thiago C. de Souza1; André Luiz M. Camelo1; Ricardo de Araújo Marques2; Luiz Ivando Pires F. Filho3; Ronald F. Pinheiro3; Elisane Longhinotti1; Helena Becker1,*


Chromatogram of thermal degradation of carbaryl in 1-naphthol when exposed to high temperature conditions and response surface plot for extraction of carbaryl.

http://dx.doi.org/10.21577/0100-4042.20170026

Publicado online: março 9, 2017
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Total access: 2692

Educação Quim. Nova 2017, 40(5), 594-601

 

Uso de nanobastões de ouro para o desenvolvimento de aulas práticas de nanotecnologia

Cyntia Silva Ferreira1,*; Luiz Orlando Ladeira2; Cristiano Fantini Leite2; Flávio Guimaraes da Fonseca3; Erica Milena de Castro Ribeiro1; Alice Freitas Versiani3; Jorge Fernando de Souza Silva1; Cíntia Lopes de Brito Magalhaes1; Breno de Mello Silva1


A practical class was proposed using gold nanorods synthesized with CTAB and functionalized with specific antibodies. The target detection was performed by analysis of the surface plasmon resonance in UV-Vis-NIR spectrophotometer.

http://dx.doi.org/10.21577/0100-4042.20170021

Publicado online: fevereiro 14, 2017
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Total access: 3141

Assuntos Gerais Quim. Nova 2017, 40(5), 602-612

 

O Visconde de Barbacena e o químico José Álvares Maciel: encontro na ciência e desencontro na política

Robson Jorge de Araújo; Carlos A. L. Filgueiras*


http://dx.doi.org/10.21577/0100-4042.20170017

Publicado online: fevereiro 14, 2017
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Total access: 1941

On-line version ISSN 1678-7064 Printed version ISSN 0100-4042
Química Nova
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