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10:58, qui nov 21

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EDIÇÃO ATUAL vol. 43, No. 10, 2020



Artigo de Capa
Quim. Nova 2020, 43(10), 1463-1481

Nanomateriais plasmônicos: Parte I. fundamentos da espectroscopia de nanopartículas e sua relação com o efeito sers

Daniel GrasseschiI; Diego P. dos SantosII,*

The excitation of localized surface plasmon modes in metal nanoparticles is the fundamental property related to applications of plasmonic nanomaterials, such as photocatalysis, chemical sensing and enhanced spectroscopies (e.g. SERS).

http://dx.doi.org/10.21577/0100-4042.20170621

Publicado online: agosto 27, 2020
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Total access: 2022

Artigo Quim. Nova 2020, 43(10), 1375-1384

 

Preparação e validação de arquivos de entrada para uso no simulador de qualidade do ar (CMAQ)

Rodrigo do P. MaiaI,*; Leonardo BaptistaI,II; Eduardo Monteiro MartinsI,III


The city of Rio de Janeiro has a special atmosphere, as it is an urban region, surrounded by forests, mountains and the sea, which allows a series of chemical reactions from different types of sources.

http://dx.doi.org/10.21577/0100-4042.20170638

Publicado online: setembro 21, 2020
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Quim. Nova 2020, 43(10), 1385-1392

 

Método de triagem de microgininas em cianobactérias por LC-MS/MS

Kazumi K. TeramotoI,*; Fabiane DorrI; Miriam SanzII; Ernani PintoI


Untargeted screening of microginin class cyanopeptides in cyanobacteria extracts by LC-MS/MS using precursor ion scan and structure elucidation based on high resolution mass spectra.

http://dx.doi.org/10.21577/0100-4042.20170640

Publicado online: setembro 21, 2020
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Total access: 1921

Quim. Nova 2020, 43(10), 1393-1396

 

Método manual para deposição de tintas fotoluminescentes baseadas em lofs mistas aplicado a codificação de documentos

Millayd M. NogueiraI; Luiz H. M. CostaI; Jakson N. C. ReisI; Antonio Marcos U. AraújoII; Érico de Moura NetoI,*; Jarley F. S. NascimentoI


This image represents the whole process developed in this study, from the synthesis to the application of the photoluminescent ink in the sheets of paper.

http://dx.doi.org/10.21577/0100-4042.20170632

Publicado online: setembro 10, 2020
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Total access: 980

Quim. Nova 2020, 43(10), 1397-1403

 

Asarone-derived phenylpropanoids and isoquinoline-derived alkaloids from the bark of Duguetia pycnastera (Annonaceae) and their cytotoxicities

César A. S. de SouzaI; Victória B. NardelliI; Weider H. P. PazI; Maria Lúcia B. PinheiroI; Ana Carolina B. da C. RodriguesII; Larissa M. BomfimII; Milena B. P. SoaresII; Daniel P. BezerraII; Jamal da S. ChaarI; Hector H. F. KoolenIII; Felipe M. A. da SilvaIV; Emmanoel Vilaça CostaI,*


Asarone-derived phenylpropanoids and isoquinoline-derived alkaloids were isolated from the bark of Duguetia pycnastera (Annonaceae) and reported for the first time in the species. The unambiguous assignments of the 1H and 13C NMR data for nornuciferidine and guatterine N-oxide were described. Additionally, the cytotoxicity of the isolated compounds (except for nornuciferidine) was investigated by the Alamar blue assay.

http://dx.doi.org/10.21577/0100-4042.20170617

Publicado online: agosto 21, 2020
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Total access: 1401

Quim. Nova 2020, 43(10), 1404-1407

 

Antipromastigote and cytotoxic activities of flavonoids from Fridericia speciosa leaves

Reinaldo R. Milani; Osvaine J. A. Alves; Camila S. Bertanha; Valéria M. M. Gimenez; Iara S. Squarisi; Heloiza D. Nicolella; Mariana C. Pagotti; Denise C. Tavares; Márcio L. A. e Silva; Wilson R. Cunha; Lizandra G. Magalhães; Ana H. Januario; Patricia M. Pauletti*


Chemical, biological, and HPLC quantification studies showed that Fredericia speciosa, mainly the EtOAc-soluble fraction, is a rich source of bioactive flavonoids.

http://dx.doi.org/10.21577/0100-4042.20170628

Publicado online: setembro 4, 2020
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Total access: 1126

Quim. Nova 2020, 43(10), 1408-1415

 

Influência da força iônica na estimativa de pKa por método voltamétrico

Priscila A. Liberato; Astréa F. de S. Silva*; Leonardo L. Okumura; Juliana A. Diniz; André Fernando de Oliveira


The common ionic strenght adjust used in voltammetric techniques causes a bias in the determination of pKa by line intersection methods.

http://dx.doi.org/10.21577/0100-4042.20170636

Publicado online: setembro 10, 2020
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Total access: 902

Quim. Nova 2020, 43(10), 1416-1420

 

An approach based on electrochemical impedance spectroscopy to study the glycerol/biodiesel gravity separation

Karen Gómez-Hernández; Rodrigo Patiño; Luis Maldonado-Lópezand; Luis Díaz-Ballote*


Electrochemical impedance spectroscopy is proposed as a novel tool to monitor the glycerol/biodiesel gravity separation.

http://dx.doi.org/10.21577/0100-4042.20170635

Publicado online: setembro 10, 2020
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Total access: 1120

Quim. Nova 2020, 43(10), 1421-1430

 

Rapid detection of vitamin c content in fruits and vegetables using a digital camera and color reaction

Wen-zhu ZhaoI; Ping-ping CaoI; Yuan-yang ZhuI; Sheng LiuI,*; Hong-Wen GaoII; Chao-qun HuangIII


The RGB and Lab values of the solution to be measured were obtained using an image acquisition device and image processing software, while the color component and standard concentration were multiply fitted to obtain the measurement model for the determination of the vitamin C content in fruits and vegetables.

http://dx.doi.org/10.21577/0100-4042.20170642

Publicado online: setembro 21, 2020
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Total access: 1437

Quim. Nova 2020, 43(10), 1431-1438

 

Characterization of aquatic organic matter in a natural environment in northeastern brazil

Adnívia S. Costa MonteiroI,*; Maria Aparecida A. SantanaII; Raisa de Siqueira Alves ChielleIII; Carlos Alexandre Borges GarciaII; José do Patrocínio Hora AlvesI


Natural organic matter (NOM) is a complex mixture of organic compounds that occurs in natural waters. The assessment of NOM characteristics is often carried out by fluorescence spectroscopy and UV-visible absorbance, and the measure of dissolved organic carbon (DOC).

http://dx.doi.org/10.21577/0100-4042.20170630

Publicado online: setembro 4, 2020
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Total access: 1037

Quim. Nova 2020, 43(10), 1439-1446

 

Polímero de impressão molecular para o tiacloprido: uma investigação teórica

Camilla Fonseca Silva; Clebio Soares Nascimento Jr.*


Based on the need for determination of thiacloprid neonicotinoid in samples of analytical interest, the rational synthesis protocol regarding the chemical nature of the functional monomer (FM), stoichiometry (MM:FM) and solvent was optimized by DFT calculations.

http://dx.doi.org/10.21577/0100-4042.20170618

Publicado online: agosto 21, 2020
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Total access: 970

Revisão Quim. Nova 2020, 43(10), 1447-1462

 

Bionanocompósitos poliméricos à base de montmorillonita - materiais de interesse contínuo

Denise B. FrançaI; Ana C. S. AlcântaraII; Edson C. Silva-FilhoIII; Maria G. FonsecaI,*


Montmorillonite/biopolymer nanocomposites is a class of materials inspired in classic montmorillonite/polyamide nanocomposite and present new properties for application in different fields including antimicrobial materials and vehicle for drugs.

http://dx.doi.org/10.21577/0100-4042.20170602

Publicado online: agosto 3, 2020
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Total access: 1162

Quim. Nova 2020, 43(10), 1482-1499

 

Nanomateriais plasmônicos: Parte II. química de coordenação de superfície e sua aplicação em sensores e catalisadores

Diego P. dos SantosI; Daniel GrasseschiII,*


The approach here presented incorporates supramolecular approach, in which nanoparticles with well-controlled features conjugated with properly chosen molecules are the basis of functional organized structures for several applications.

http://dx.doi.org/10.21577/0100-4042.20170629

Publicado online: setembro 4, 2020
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Nota Técnica Quim. Nova 2020, 43(10), 1500-1504

 

Autenticação de orégano (Origanum vulgare L.) orgânico utilizando espectroscopia NIR e quimiometria

Ana Sophia Tovar Fernandez; Andressa Rafaella da Silva Bruni; Vitória Maria Almeida Teodoro de Oliveira; Paulo Henrique Março; Patrícia Valderrama*


An approach was proposed for authentication of organic oregano through the NIR and chemometrics.

http://dx.doi.org/10.21577/0100-4042.20170616

Publicado online: agosto 21, 2020
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Total access: 884

Educação Quim. Nova 2020, 43(10), 1505-1509

 

Extraction and identification of formulations of anabolic androgenic steroids: a forensic educational approach

Lucas M. Berneira; Marina Ritter; Caroline C. da Silva; Tais Poletti; Luan F. Passos; Bruno N. da Rosa; Marco A. Z. dos Santos; Claudio M. P. de Pereira*


A set of three experiments was developed and applied to undergraduate students of Forensic Chemistry dealing with visual inspection of apprehended formulations of anabolic androgenic steroids as well as chemical identification by Infrared Spectroscopy and Gas Chromatography-Mass Spectrometry. Moreover, the classroom evaluated the extraction of steroidal active ingredients by ultrasonic and microwave-assisted extraction.

http://dx.doi.org/10.21577/0100-4042.20170607

Publicado online: agosto 7, 2020
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Total access: 348

Quim. Nova 2020, 43(10), 1510-1521

 

Green chemistry teaching for sustainability in papers published by the journal of chemical education

Carlos Alberto MarquesI,*; Leonardo V. MarcelinoI; Érica D. S. DiasII; Patricia Link RüntzelII; Leila Cristina Aoyama Barbosa SouzaIII; Adélio MachadoIV


This paper analyses 286 papers on Green Chemistry published in the Journal of Chemical Education regarding the relationships between Green Chemistry, Sustainability and Systems Thinking present in teaching approaches.

http://dx.doi.org/10.21577/0100-4042.20170612

Publicado online: agosto 13, 2020
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Total access: 1677

Quim. Nova 2020, 43(10), 1522-1528

 

Utilização de biomassa em aulas de graduação de química orgânica experimental: extração de flavonoides a partir de resíduos de cascas de frutas cítricas

Mauricio M. VictorI,II,III,*; Juliana L. LeiteI,II; Gabriel S. RamosI,II; Jorge M. DavidI,III; Klauber V. CardosoI


A well succeeded and useful flavonoid extraction experiment from citrus waste biomass employing common solvents for undergraduate experimental classes is described.

http://dx.doi.org/10.21577/0100-4042.20170609

Publicado online: agosto 7, 2020
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Total access: 1551

Quim. Nova 2020, 43(10), 1529-1537

 

A problematização da abordagem temática na formação inicial de professores de química

Renata Aragão da Silveira; Lya Piaia; Fábio Peres Gonçalves*


This work about training of chemistry teachers was guided by assumptions from the perspective of the teacher as researcher of the practice itself and by Pedagogy of Paulo Freire.

http://dx.doi.org/10.21577/0100-4042.20170614

Publicado online: agosto 21, 2020
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Total access: 998

Assuntos Gerais Quim. Nova 2020, 43(10), 1538-1548

 

Patentometria: uma ferramenta indispensável no estudo de desenvolvimento de tecnologias para a indústria química

Marcelo Gomes SpezialiI,*; Raphael da Silva NascimentoII


Big data patent analysis as an essential tool for the understanding of the technological maturity, competitors, and strategic intelligence for technologies in chemistry.

http://dx.doi.org/10.21577/0100-4042.20170620

Publicado online: agosto 27, 2020
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Total access: 1246

Errata Quim. Nova 2020, 43(10), 1549

 

On-line version ISSN 1678-7064 Printed version ISSN 0100-4042
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