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10:42, qui nov 21

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EDIÇÃO ATUAL vol. 45, No. 8, 2022



Artigo de Capa
Quim. Nova 2022, 45(8), 959-976

N-nitrosaminas em medicamentos: um problema atual, uma realidade antiga

Tharcilla de Castro AglioI; Vinicíus DinizI; Maria Fernanda Araujo Vieira MatosI; Paulo Pires Cesar RosaII; Susanne RathI,*

http://dx.doi.org/10.21577/0100-4042.20170894

Publicado online: abril 12, 2022
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Total access: 2610

Artigo de Contra Capa
Quim. Nova 2022, 45(8), 994-1003

Avaliação rápida da qualidade do óleo vegetal isolante de transformador por espectroscopia ftir e quimiometria

Nathália Vieira BarbosaI,II,*; Larissa Batista dos SantosIII; Lucas Junji SeguchiIV; Beatriz Costa e SilvaV; Thaís Lamoglia de CarvalhoVI; Estácio Tavares Wanderley NetoIV; Rossano GimenesI; Melina Espanhol SoaresI; Ana Júlia AraujoI; Flávio Soares SilvaI; Mariana Ramos AlmeidaIII; Milady Renata Apolinário da SilvaI

A simple, fast, and non-destructive method was developed for evaluation of the quality of insulating vegetable oil from power transformers, using FTIR spectroscopy combined with chemometrics.

http://dx.doi.org/10.21577/0100-4042.20170914

Publicado online: junho 15, 2022
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Total access: 780

Artigo Quim. Nova 2022, 45(8), 901-905

 

Effect of reaction conditions on particle size of ZnO nanoparticles via controlled precipitation method and in-vitro antibacterial capacity

Miguel A. Pedroza ToscanoI; Rodolfo Salazar PeñaI; Martín Rabelero VelascoII; José J. Ibarra MontalvoIII; Jesús A. Aréchiga GuzmánIII; Susana López CuencaIII,*


Spheroidal nanoparticles of ZnO are obtained from zinc nitrate and ammonium carbonate, via controlled precipitation. Effects of the reaction parameters and the antimicrobial effect of the material are studied.

http://dx.doi.org/10.21577/0100-4042.20170881

Publicado online: março 24, 2022
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Total access: 984

Quim. Nova 2022, 45(8), 906-912

 

Estudo da atividade antitumoral de um novo complexo de Ru3+: uma proposta para o design de metalofármacos de baixa toxicidade

Maria Helena P. S. de AndradeI; Jaciana S. AguiarII; Teresinha G. da SilvaII; Jandyson M. SantosI; Wagner E. SilvaI; Mônica F. BelianI,*


The Ru3+ complex proposed presented antitumor activity higher to cisplatin, and a significant reduction in acute toxicity once compared to antitumor drug (category = 1), being considered the Na[Ru(H2O)2(Mal-κ2O)2] complex in the category = 4.

http://dx.doi.org/10.21577/0100-4042.20170886

Publicado online: abril 5, 2022
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Total access: 732

Quim. Nova 2022, 45(8), 913-920

 

Vibration characteristics, chemical bonds and weak interactions of 4- and 5-hydroxysalicylic acid investigated by terahertz spectroscopy and density functional theory

Yuan TangI; Zhi LiI,II,*; Yan GuoII; Xianhua YinI; Shan TuIII; Dapeng ZhangI


The THz spectroscopy was used to detect the 4- and 5-hydroxysalicylic acid isomers. The vibrational modes of two isomers were studied by PED analysis. Chemical bonds and weak interactions of two isomers were analyzed using IRI methods.

http://dx.doi.org/10.21577/0100-4042.20170896

Publicado online: abril 19, 2022
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Total access: 617

Quim. Nova 2022, 45(8), 921-928

 

Liberação lenta do óleo de copaíba adsolubilizado em hidróxidos duplos lamelares: um material promissor para pomadas cutâneas

Daiane A. R. NogueiraI,*; Silvia JaergerI; Margani Taise FinII; Rubiana Mara MainardesII; Leandro ZattaIII; Luciano TormenIV; Rafael MarangoniI


Copaiba oil was adsolubilized into ZnAl layered double hydroxides synthesized with dodecyl sulfate anions. The slow-release experiments have shown de potentiality to use the layered double hydroxides filled with copaiba oil like a carrier in ointments.

http://dx.doi.org/10.21577/0100-4042.20170900

Publicado online: maio 18, 2022
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Total access: 716

Quim. Nova 2022, 45(8), 929-934

 

Estudo one-pot da aplicação do catalisador de Grubbs de primeira geração em reações de metátese da piperina e eugenol: a influência da ligação dupla terminal

Ana K. B. CostaI; Kerlane A. FernandesI; Vanessa B. VieiraI; Aline A. C. FrançaII; Wanessa A. Limaa; Pedro M. de Almeidaa; José M. E. de MatosII; Benedito S. L. NetoIII; José L. S. SáI,*; Francielle A. MartinsI


The present study describes the one-pot metathesis reaction between piperine and eugenol, in the presence of the 1st generation Grubbs catalyst. The results (isomerization, dimerization) are discussed in terms of the influence of the double bond.

http://dx.doi.org/10.21577/0100-4042.20170901

Publicado online: maio 18, 2022
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Total access: 892

Quim. Nova 2022, 45(8), 935-940

 

Addition of natural extracts with antioxidant properties in biodiesel: analysis by neural networks of the multilayer perceptron type

Marco A. J. Clementea; Heloisa H. P. SilvaI; Júlia W. CamposI; Ana C. G. MantovaniII; Dionisio BorsatoI,*


Biodiesel samples in mixtures with natural extracts of senna leaves, hibiscus flowers and blackberry fruits were analyzed and studied using neural networks of the multilayer perceptron type.

http://dx.doi.org/10.21577/0100-4042.20170902

Publicado online: maio 18, 2022
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Total access: 934

Quim. Nova 2022, 45(8), 941-948

 

Biodegradable sodium carboxymethyl cellulose membranes containing Melaleuca essential oils for wound care material

Silvane Holanda SoaresI; Hugo Cavalcante PeixotoI; Edlene Ribeiro PrudencioII; Rosa Helena LucheseII; Robson AraújoIII; Ana Paula Duarte MoreiraIII; Leonardo Sales AraújoIII; Luiz Henrique Guerreiro RosadoIV; Rommel Sauerbronn da CunhaV; Rosane Nora CastroVI; Renata Nunes OliveiraI,*


Melaleuca (tea tree) essential oil, with high proportion of 1,8-cineol/terpinen-4-ol, was loaded to NaCMC gels. The samples presented hydrolitic degradation; relaxation mechanism dictated swelling capacity and oil delivery; and the samples were active against S.aureus.

http://dx.doi.org/10.21577/0100-4042.20170903

Publicado online: maio 18, 2022
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Total access: 672

Revisão Quim. Nova 2022, 45(8), 946-958

 

O mercado de óleos essenciais no Brasil e no mundo na última década

Humberto R. BizzoI,II,*; Claudia M. RezendeII


Brazil is an important player in the essential oils market, with a positive impact the balance of trade for this class of goods.

http://dx.doi.org/10.21577/0100-4042.20170889

Publicado online: abril 5, 2022
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Total access: 2027

Quim. Nova 2022, 45(8), 977-993

 

Pavonia Cav. species (Malvaceae sensu lato) as source of new drugs: a review

Janderson Barbosa Leite de AlbuquerqueI; Camila Macaúbas da SilvaI; Diégina Araújo FernandesI; Pedro Isaac Vanderlei de SouzaII; Maria de Fátima Vanderlei de SouzaI,*


Bibliographic analysis of the traditional use, chemical and pharmacological profile of Pavonia Cav. species (Malvaceae sensu lato) searching for new drug sources.

http://dx.doi.org/10.21577/0100-4042.20170897

Publicado online: abril 19, 2022
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Total access: 606

Nota Técnica Quim. Nova 2022, 45(8), 1004-1009

 

Development and optimization of a spectrophotometric method with cloud point extraction for determination of gadolinium

Jany Hellen F. de JesusI,II,#; Rennan Geovanny O. AraujoIII,IV,*; Luciane Pimenta C. RomãoI


A new spectrophotometric method based on cloud-point extraction for the determination of gadolinium in water and contrast agents was successfully optimized.

http://dx.doi.org/10.21577/0100-4042.20170915

Publicado online: junho 15, 2022
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Total access: 584

Educação Quim. Nova 2022, 45(8), 1010-1019

 

Química verde e a tabela periódica de Anastas e Zimmerman: tradução e alinhamentos com o desenvolvimento sustentável

Carlos Alberto da Silva JúniorI,II; Dosil Pereira de JesusI,#; Gildo Girotto JúniorI,*


The Periodic Table of the Elements of Green and Sustainable Chemistry is an interdisciplinary encyclopedia contributing to Sustainable Development. This paper presents a translation of this alternative table into the Portuguese language and an alignment discussion with a sustainable future.

http://dx.doi.org/10.21577/0100-4042.20170893

Publicado online: abril 8, 2022
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Total access: 1988

Quim. Nova 2022, 45(8), 1020-1030

 

Robótica educacional, ensino de química e aprendizagem cooperativa: uma proposta para o curso de ensino superior em Engenharia Civil

Ricardo Silvério Gomes Pinheiro; Márlon Herbert Flora Barbosa Soares*


Educational robotics and educational cooperation combined with Chemistry Teaching in a Civil Engineering course, culminated in learning of university students made a robot to identify electrochemical corrosion in concrete metallic structures.

http://dx.doi.org/10.21577/0100-4042.20170906

Publicado online: maio 26, 2022
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Total access: 623

Assuntos Gerais Quim. Nova 2022, 45(8), 1031-1038

 

What is new in non-chromatographic flavonoid purification?

Leonardo de Oliveira Aguiar; Clara Ribeiro do Espírito Santo D'Onofrio; Jorge Mauricio David*


The state of the art of new techniques for flavonoids separation and purification: employing ionic liquids, eutectic solvent, and chelating agents.

http://dx.doi.org/10.21577/0100-4042.20170918

Publicado online: junho 30, 2022
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Total access: 559

On-line version ISSN 1678-7064 Printed version ISSN 0100-4042
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